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- W2315413535 abstract "Irrespective of the ratio of the reactands AsBr 3 and mesMgBr (mes = mesityl), two products are formed in THF solution: dimesitylarsenic bromide and a magnesium bromoarsenate of composition MgAs 5 Br 17 · n THF. The latter, on crystallization from acetonitrile, yields [Mg(NCMe) 4 (THF) 2 ][As 3 Br 11 ]. The anion of this salt can be described as derived from three face sharing AsBr 6 octahedra. The lone pair of electrons at the As atoms is stereochemically not active." @default.
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- W2315413535 date "1999-05-01" @default.
- W2315413535 modified "2023-09-26" @default.
- W2315413535 title "Unerwartete Reaktionsprodukte bei der Umsetzung von Mesitylmagnesiumbromid mit Arsentribromid / Unexpected Products from the Reaction of Mesitylmagnesium Bromide and Arsenic Tribromide" @default.
- W2315413535 doi "https://doi.org/10.1515/znb-1999-0506" @default.
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