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- W2315432815 abstract "Dodecylbenzenesulfonate (DBS) modified NiRTi layered double hydroxides (LDHs) with different Ni/Ti molar ratios were prepared as hydrophobic organics sorbent by one-step co-precipitation method. The basal spacing of DBS−NiRTi (d003 = 2.99−3.54 nm) is significantly increased compared with cyanate-intecalated Ni5Ti−LDH (0.73 nm) due to the intercalation of surfactant anions between the LDH layers. The greatly enhanced contact angle (123.5−144.2°) for water and the reduced surface area (1.72−3.25 m2/g) of DBS−NiRTi nanocomposites demonstrate their strong hydrophobic property. The highest sorption capacity for pentachlorophenol (PCP) of DBS−Ni5Ti among all samples is intimately related to its stacking model of the interlayer hydrophobic moiety and organic carbon content. The linear model well-fits for PCP sorption isotherms on DBS−NiRTi (R2 > 0.96), implying a partitioning sorption process. Along with the effect of medium pH and temperature on PCP sorption−desorption study on DBS−Ni5Ti, an adsolubilization mechanism, an exothermic sorption nature, and a significant hysteresis phenomenon during sorption−desorption process are revealed." @default.
- W2315432815 created "2016-06-24" @default.
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- W2315432815 date "2011-04-01" @default.
- W2315432815 modified "2023-10-14" @default.
- W2315432815 title "Adsorption of Pentachlorophenol from Aqueous Solution on Dodecylbenzenesulfonate Modified Nickel−Titanium Layered Double Hydroxide Nanocomposites" @default.
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- W2315432815 doi "https://doi.org/10.1021/ie101766e" @default.
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