FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2315511482> ?p ?o ?g. }

• W2315511482 endingPage "1452" @default.
• W2315511482 startingPage "1440" @default.
• W2315511482 abstract "Here we present the first synthetic route to bis(η5:η1-pentafulvene)zirconium complexes as well as investigations of several consecutive reactions. Sodium amalgam reduction of ZrCl4 in the presence of a bulky substituted pentafulvene in THF leads to the formation of [η5:η1-C5H4═CR2]2Zr(THF) (2a, R = p-tol; 2b, R = Ph). The molecular structure of 2a has been determined by single-crystal X-ray diffraction and exhibits an unusually large Zr–Cexo distance (2.708(2) Å) caused by the bulky substituents at the exocyclic carbon, which allows THF coordination. The reaction of 2a with H-acidic compounds such as hydrogen chloride, amines, and water were examined: addition of HCl leads to the dichloride complex [η5-C5H4-CH(p-tol)2]2ZrCl2 (3) and treatment of 2a with p-methylaniline forms the bis-amide complex [η5-C5H4-CH(p-tol)2]2Zr(NH-p-tol)2 (4), whereas addition of the sterically more demanding dicyclohexylamine furnishes the monoamide complex [η5:η1-C5H4═C(p-tol)2][η5-C5H4-CH(p-tol)2]Zr(NCy2) (5). The cyclotrimeric compound {[η5-C5H4-CH(p-tol)2]2Zr(μ-O)}3 (6) is obtained by reaction of 2a with water. Moreover, insertion reactions of CX multiple bonds (X = N, O) into the Zr–Cexo(Fv) bond of 2a result in the formation of the zirconacycles [η5:η1-C5H4-C(p-tol)2-C(C6H4Cl)═N−]2Zr (7), [η5:η1-C5H4-C(p-tol)2-MeC4H6N−]2Zr (8), and [η5:η1-C5H4-C(p-tol)2-C(Ph)2O−]2Zr (9). Finally, 2a is a valuable agent for the activation of molecular hydrogen under ambient conditions. In this regard, only one pentafulvene ligand per zirconium atom is protonated and the dinuclear zirconium hydride complex {[η5:η1-C5H4═C(p-tol)2][η5-C5H4-CH(p-tol)2]Zr(μ-H)}2 (10) is isolated. All compounds were confirmed by single-crystal X-ray diffraction and NMR spectroscopic measurements." @default.
• W2315511482 created "2016-06-24" @default.
• W2315511482 creator A5016621324 @default.
• W2315511482 creator A5023370187 @default.
• W2315511482 creator A5027772285 @default.
• W2315511482 creator A5047742057 @default.
• W2315511482 creator A5056628979 @default.
• W2315511482 creator A5059186889 @default.
• W2315511482 creator A5072335092 @default.
• W2315511482 creator A5073428483 @default.
• W2315511482 date "2014-03-12" @default.
• W2315511482 modified "2023-09-27" @default.
• W2315511482 title "Synthesis and Reactivity of Bis(η⁵:η¹-pentafulvene)zirconium Complexes" @default.
• W2315511482 cites W1580561783 @default.
• W2315511482 cites W1965484920 @default.
• W2315511482 cites W1967154682 @default.
• W2315511482 cites W1969524939 @default.
• W2315511482 cites W1972293866 @default.
• W2315511482 cites W1972929500 @default.
• W2315511482 cites W1974232525 @default.
• W2315511482 cites W1974833695 @default.
• W2315511482 cites W1976584554 @default.
• W2315511482 cites W1976625372 @default.
• W2315511482 cites W1979457509 @default.
• W2315511482 cites W1980942084 @default.
• W2315511482 cites W1982082455 @default.
• W2315511482 cites W1983777702 @default.
• W2315511482 cites W1987757932 @default.
• W2315511482 cites W1991282075 @default.
• W2315511482 cites W1994280706 @default.
• W2315511482 cites W1995354451 @default.
• W2315511482 cites W1996605144 @default.
• W2315511482 cites W2000550683 @default.
• W2315511482 cites W2002067802 @default.
• W2315511482 cites W2004738397 @default.
• W2315511482 cites W2005758035 @default.
• W2315511482 cites W2005786057 @default.
• W2315511482 cites W2006370825 @default.
• W2315511482 cites W2009246196 @default.
• W2315511482 cites W2011667896 @default.
• W2315511482 cites W2011782218 @default.
• W2315511482 cites W2015843692 @default.
• W2315511482 cites W2018041367 @default.
• W2315511482 cites W2018680050 @default.
• W2315511482 cites W2018717846 @default.
• W2315511482 cites W2019132898 @default.
• W2315511482 cites W2025960378 @default.
• W2315511482 cites W2026228805 @default.
• W2315511482 cites W2027826335 @default.
• W2315511482 cites W2027847617 @default.
• W2315511482 cites W2030648539 @default.
• W2315511482 cites W2032415031 @default.
• W2315511482 cites W2041421030 @default.
• W2315511482 cites W2045596821 @default.
• W2315511482 cites W2046972383 @default.
• W2315511482 cites W2048097358 @default.
• W2315511482 cites W2048904716 @default.
• W2315511482 cites W2055423055 @default.
• W2315511482 cites W2055975105 @default.
• W2315511482 cites W2057248744 @default.
• W2315511482 cites W2057543290 @default.
• W2315511482 cites W2058057389 @default.
• W2315511482 cites W2058605846 @default.
• W2315511482 cites W2063295441 @default.
• W2315511482 cites W2064629854 @default.
• W2315511482 cites W2068369018 @default.
• W2315511482 cites W2069222935 @default.
• W2315511482 cites W2071197005 @default.
• W2315511482 cites W2071268967 @default.
• W2315511482 cites W2078593705 @default.
• W2315511482 cites W2080766117 @default.
• W2315511482 cites W2081067409 @default.
• W2315511482 cites W2081671121 @default.
• W2315511482 cites W2084844334 @default.
• W2315511482 cites W2085925264 @default.
• W2315511482 cites W2089253408 @default.
• W2315511482 cites W2089978027 @default.
• W2315511482 cites W2090665235 @default.
• W2315511482 cites W2096625306 @default.
• W2315511482 cites W2097306092 @default.
• W2315511482 cites W2098626631 @default.
• W2315511482 cites W2108538431 @default.
• W2315511482 cites W2110965866 @default.
• W2315511482 cites W2129937857 @default.
• W2315511482 cites W2133269608 @default.
• W2315511482 cites W2160180943 @default.
• W2315511482 cites W2162766704 @default.
• W2315511482 cites W2163595594 @default.
• W2315511482 cites W2171942297 @default.
• W2315511482 cites W2315113558 @default.
• W2315511482 cites W2331613503 @default.
• W2315511482 cites W2951025099 @default.
• W2315511482 cites W2952934938 @default.
• W2315511482 cites W4241685322 @default.
• W2315511482 cites W4241744422 @default.
• W2315511482 cites W4245936730 @default.
• W2315511482 cites W4249590384 @default.
• W2315511482 doi "https://doi.org/10.1021/om500031s" @default.

• next