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• W2315613215 endingPage "20379" @default.
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• W2315613215 abstract "We have determined the surface hydride composition of amorphous and crystalline Si nanoparticles (NPs) (3–5 nm) synthesized in a low-temperature SiH4/Ar plasma using in situ attenuated total reflection Fourier-transform infrared spectroscopy and H2 thermal effusion measurements. With increasing power to the plasma source, the particles transition from amorphous to crystalline with a corresponding increase in the fraction of SiH species on the surface. The surface hydride composition indicates that Si NPs synthesized at higher plasma powers crystallize in the gas-phase due to a greater degree of plasma-induced heating, which enhances the desorption rates for SiH2 and SiH3. Furthermore, these Si NPs do not contain any detectable H in the bulk." @default.
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• W2315613215 date "2011-09-29" @default.
• W2315613215 modified "2023-09-27" @default.
• W2315613215 title "Surface Hydride Composition of Plasma-Synthesized Si Nanoparticles" @default.
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• W2315613215 doi "https://doi.org/10.1021/jp2028005" @default.
• W2315613215 hasPublicationYear "2011" @default.
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