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• W2315658941 abstract "Abstract Iridium(I) (acetylacetonato)(1,5-cyclooctadiene) complex, Ir(C5H7O2)(C8H12), was synthesized and characterized by elemental CH-analysis, NMR, X-ray spectroscopy. The heat capacity of compound Ir(C5H7O2)(C8H12) has been measured by the adiabatic method within the temperature range (6–318) K. The thermodynamic functions: entropy, enthalpy and reduced Gibbs energy have been calculated. They have the following values at 298.15 K: C°p = (323.6 ± 0.6) J K−1 mol−1, Δ0298.15S°m = (347.0 ± 0.9) J K−1 mol−1, Δ0298.15H°m = (50.82 ± 0.09) kJ mol−1, Φ°m = (176.5 ± 0.7) J K−1 mol−1. The value of the absolute entropy were used to calculate the entropy of formation of Ir(C5H7O2)(C8H12) at T = 298.15 K. An anomaly of heat capacity has been discovered with a maximum at Tc = 287.20 K, which points to the phase transition of the complex. Anomalous contributions to entropy and enthalpy have been revealed." @default.
• W2315658941 created "2016-06-24" @default.
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• W2315658941 date "2016-08-01" @default.
• W2315658941 modified "2023-09-27" @default.
• W2315658941 title "Low-temperature heat capacity of Ir(C 5 H 7 O 2 )(C 8 H 12 )" @default.
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• W2315658941 doi "https://doi.org/10.1016/j.jct.2016.03.044" @default.
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