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- W2315666768 abstract "α-Mannopyranosyl phosphosugars are obtained in 61−90% yields from 4,6-O-benzylidene-protected mannosyl thioglycosides bearing ester functionality in the 3-O-position by coupling reactions with ammonium salts of phosphosugars on activation with 1-benzenesulfinyl piperidine, 2,4,6-tri-tert-butylpyrimidine, and trifluoromethanesulfonic anhydride. Due to the presence of the disarming ester group, only the formation of the α-isomer was observed." @default.
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- W2315666768 date "2009-11-19" @default.
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- W2315666768 title "Highly Stereoselective Synthesis of α-<scp>d</scp>-Mannopyranosyl Phosphosugars" @default.
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- W2315666768 doi "https://doi.org/10.1021/jo902254w" @default.
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