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- W2315667736 abstract "Recently, nanoconfined poly(vinylidene fluoride) (PVDF) and its random copolymers have attracted substantial attention in research. In addition to the drastic change in crystallization kinetics, major interest lies in crystal orientation and polymorphism in order to understand whether enhanced piezoelectric and ferroelectric properties can be achieved. For example, PVDF has been two-dimensionally (2D) confined in cylindrical nanopores of anodic aluminum oxide (AAO) with various pore diameters. The crystal c-axis becomes perpendicular to the cylinder axes, which favors dipole switching in the impregnated AAO membrane. However, no polar phases have been obtained from 2D confinement even down to 35 nm pores after melt recrystallization. In this work, we realized three-dimensionally (3D) confined crystallization of PVDF in 180 nm nanospheres by employing a facile emulsifier-free batch seeded emulsion polymerization to prepare PVDF@polystyrene (PS) core–shell particles. Influences of polymerization temperature..." @default.
- W2315667736 created "2016-06-24" @default.
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- W2315667736 date "2014-04-11" @default.
- W2315667736 modified "2023-09-29" @default.
- W2315667736 title "Composite Poly(vinylidene fluoride)/Polystyrene Latex Particles for Confined Crystallization in 180 nm Nanospheres via Emulsifier-Free Batch Seeded Emulsion Polymerization" @default.
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- W2315667736 doi "https://doi.org/10.1021/ma500249p" @default.
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