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- W2315667946 abstract "In order to estimate the interparticle reaction rate, an examination of kinetic models was undertaken for three typical uni-directional diffusion systems, Fe2O3-V2O5, Al2O3-CuO and Al2O3-ZnO. Hao-Tanaka's concentric spherical model is found to be valid for these systems based on the difference in the dependence of the reaction rate upon the particle radius, the radius ratio and the molar ratio in the samples. This can be regarded as a generalized model which enables us to the evaluate interparticle reaction rate.In conventional spherical shell models, the Ginstling-Brounshtein's model is sound in material balance, but with it we are unable to assess the interparticle reaction rate, since the contact points between the particles are not taken into account. Jander's model is most commonly used to represent the reaction rate, however it cannot be used to estimate the value due to serious irrationality in the material balance." @default.
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- W2315667946 date "1993-01-01" @default.
- W2315667946 modified "2023-09-24" @default.
- W2315667946 title "The Estimation of the Interparticle Reaction Rate by the Introduction of a Number of Contact Points in Uni-directional Diffusion System." @default.
- W2315667946 doi "https://doi.org/10.4164/sptj.30.9_627" @default.
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