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- W2315671397 abstract "Abstract UV-Bestrahlung des neuen [2-Methoxy-α-oxo-phenylmethan]-diphenylphosphins (1) in Benzol führt zur Bildung von Produkten durch α-Spaltung (3) und Photosubstitution (4) sowie zum Phosphinoxid 2. Die Genese von 2 wird durch photoinduzierten 1,2-Sauerstofftransfer aus der Carbonylgruppe auf den Phosphor in 1, neuartige Fragmentierung unter Bildung der Phosphinigsäure 6 und Addition derselben an Aceton erklärt. Die Struktur von 2 wird u. a. durch Röntgenstrukturanalyse belegt. UV irradiation of the new [2-methoxy-α-oxo-phenylmethane]-diphenylphosphine (1) in benzene leads to products via α-cleavage (3) and photosubstitution (4) as well as to the phosphine oxide 2. The genesis of 2 is interpreted by photoinduced 1,2-transfer of oxygen from the carbonyl function onto the phosphorous atom in 1, a novel fragmentation under formation of the phosphine oxide 6 and its addition to aceton. The structure of 2 is based on among other methods X-ray analysis." @default.
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- W2315671397 date "1980-07-01" @default.
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- W2315671397 title "ORGANISCHE PHOTOCHEMIE, XXXVII<sup>1,2</sup>PHOTOFRAGMENTIERUNG EINES AROYL-DIPHENYLPHOSPHINS IN DIPHENYLPHOSPHINIGSÄURE" @default.
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- W2315671397 doi "https://doi.org/10.1080/03086648008078215" @default.
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