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• W2315672457 abstract "A simple method for addition of homoallylic fragments to aldehydes is described. Cyclopropanated allylboration reagents react with aldehydes in the presence of PhBCl2 to give high yields of bishomoallyl alcohols. Cyclopropanated cis- and trans-crotyl reagents afford the corresponding 1,3-anti- and 1,3-syn-methyl-substituted “homocrotylated” alcohols with high selectivity, consistent with a Zimmerman–Traxler transition state. Accordingly, the optically active α-substituted reactant affords the E-substituted product in 97:3 er." @default.
• W2315672457 created "2016-06-24" @default.
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• W2315672457 date "2011-10-27" @default.
• W2315672457 modified "2023-10-15" @default.
• W2315672457 title "Homoallylboration and Homocrotylboration of Aldehydes" @default.
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• W2315672457 doi "https://doi.org/10.1021/ja2048682" @default.
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