FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2315676840> ?p ?o ?g. }

• W2315676840 endingPage "5523" @default.
• W2315676840 startingPage "5513" @default.
• W2315676840 abstract "We show that segmental orientation correlations, arising from network constraints and reflected in NMR observables such as the apparent proton residual dipolar coupling constant (RDCC), are sensitive to the thermodynamic state of a swollen network. The RDCC is proportional to a dynamic tensor order parameter of the network chain, which depends upon the fluctuation statistics of a network chain subject to swelling-induced stretching and excluded-volume interactions. The correlation of its value at swelling equilibrium with the corresponding degree of swelling for different networks directly reflects the value of the thermodynamic interaction parameter. A description of the phenomenon based on scaling theory allows for conclusions on the limited validity of the classical Flory–Rehner (FR) model for the good-solvent case. Our study is supplemented by temperature-dependent swelling experiments of different PDMS networks in various solvents, analyzed via a novel construction of solvent-independent swelling master curves, which also emphasize deviations from the FR model for good solvents and further confirm previous reports on concentration- or cross-linking-dependent interaction parameters. We rationalize the failure of the FR model for the good-solvent case in terms of the ratio of the network correlation length and the thermal blob size." @default.
• W2315676840 created "2016-06-24" @default.
• W2315676840 creator A5013584939 @default.
• W2315676840 creator A5028847808 @default.
• W2315676840 creator A5055541111 @default.
• W2315676840 date "2012-06-29" @default.
• W2315676840 modified "2023-09-23" @default.
• W2315676840 title "Thermodynamics of Swollen Networks As Reflected in Segmental Orientation Correlations" @default.
• W2315676840 cites W1545125692 @default.
• W2315676840 cites W1672997411 @default.
• W2315676840 cites W1967542656 @default.
• W2315676840 cites W1968661405 @default.
• W2315676840 cites W1971379641 @default.
• W2315676840 cites W1972675654 @default.
• W2315676840 cites W1979321096 @default.
• W2315676840 cites W1979908328 @default.
• W2315676840 cites W1981893596 @default.
• W2315676840 cites W1985136187 @default.
• W2315676840 cites W1996489994 @default.
• W2315676840 cites W2005305100 @default.
• W2315676840 cites W2007616173 @default.
• W2315676840 cites W2014102237 @default.
• W2315676840 cites W2016636059 @default.
• W2315676840 cites W2018339384 @default.
• W2315676840 cites W2021025092 @default.
• W2315676840 cites W2025651014 @default.
• W2315676840 cites W2026575097 @default.
• W2315676840 cites W2036823634 @default.
• W2315676840 cites W2039289890 @default.
• W2315676840 cites W2045144084 @default.
• W2315676840 cites W2046424036 @default.
• W2315676840 cites W2046586675 @default.
• W2315676840 cites W2049995806 @default.
• W2315676840 cites W2051626085 @default.
• W2315676840 cites W2052673866 @default.
• W2315676840 cites W2054314508 @default.
• W2315676840 cites W2056169647 @default.
• W2315676840 cites W2069374142 @default.
• W2315676840 cites W2077073607 @default.
• W2315676840 cites W2082018151 @default.
• W2315676840 cites W2082197290 @default.
• W2315676840 cites W2082743808 @default.
• W2315676840 cites W2085155739 @default.
• W2315676840 cites W2086435517 @default.
• W2315676840 cites W2091779578 @default.
• W2315676840 cites W2094659524 @default.
• W2315676840 cites W2169667105 @default.
• W2315676840 cites W2326384925 @default.
• W2315676840 cites W2332324726 @default.
• W2315676840 doi "https://doi.org/10.1021/ma3009004" @default.
• W2315676840 hasPublicationYear "2012" @default.
• W2315676840 type Work @default.
• W2315676840 sameAs 2315676840 @default.
• W2315676840 citedByCount "25" @default.
• W2315676840 countsByYear W23156768402012 @default.
• W2315676840 countsByYear W23156768402013 @default.
• W2315676840 countsByYear W23156768402014 @default.
• W2315676840 countsByYear W23156768402015 @default.
• W2315676840 countsByYear W23156768402016 @default.
• W2315676840 countsByYear W23156768402017 @default.
• W2315676840 countsByYear W23156768402018 @default.
• W2315676840 countsByYear W23156768402019 @default.
• W2315676840 crossrefType "journal-article" @default.
• W2315676840 hasAuthorship W2315676840A5013584939 @default.
• W2315676840 hasAuthorship W2315676840A5028847808 @default.
• W2315676840 hasAuthorship W2315676840A5055541111 @default.
• W2315676840 hasConcept C121332964 @default.
• W2315676840 hasConcept C121864883 @default.
• W2315676840 hasConcept C159985019 @default.
• W2315676840 hasConcept C16345878 @default.
• W2315676840 hasConcept C173523689 @default.
• W2315676840 hasConcept C178790620 @default.
• W2315676840 hasConcept C185592680 @default.
• W2315676840 hasConcept C192562407 @default.
• W2315676840 hasConcept C20556612 @default.
• W2315676840 hasConcept C2524010 @default.
• W2315676840 hasConcept C2778540859 @default.
• W2315676840 hasConcept C2780471494 @default.
• W2315676840 hasConcept C32848918 @default.
• W2315676840 hasConcept C33923547 @default.
• W2315676840 hasConcept C521977710 @default.
• W2315676840 hasConcept C54516573 @default.
• W2315676840 hasConcept C62520636 @default.
• W2315676840 hasConcept C97355855 @default.
• W2315676840 hasConcept C98765843 @default.
• W2315676840 hasConcept C99844830 @default.
• W2315676840 hasConceptScore W2315676840C121332964 @default.
• W2315676840 hasConceptScore W2315676840C121864883 @default.
• W2315676840 hasConceptScore W2315676840C159985019 @default.
• W2315676840 hasConceptScore W2315676840C16345878 @default.
• W2315676840 hasConceptScore W2315676840C173523689 @default.
• W2315676840 hasConceptScore W2315676840C178790620 @default.
• W2315676840 hasConceptScore W2315676840C185592680 @default.
• W2315676840 hasConceptScore W2315676840C192562407 @default.
• W2315676840 hasConceptScore W2315676840C20556612 @default.
• W2315676840 hasConceptScore W2315676840C2524010 @default.
• W2315676840 hasConceptScore W2315676840C2778540859 @default.
• W2315676840 hasConceptScore W2315676840C2780471494 @default.

• next