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- W2315676964 abstract "We declare after 40 years of a convention on the structure of allylic intermediates on ZnO surface that the surface allylzinc species exists in the form of σ,π-allyl rather than exclusively as the π-allyl complex as implied by Dent and Kokes (J. Am. Chem. Soc., 1970, 92, 1092). Olefin interaction with ZnO has been monitored by 13C cross-polarization magic angle spinning NMR. NMR shows that dissociative adsorption of propene and n-butene on ZnO surface results in the formation of carbanionic allylzinc complexes with a η1,η2-like fashion of allyl bonding to the zinc cations (σ,π-allyls). Formation of π-allylzinc complex (η3-like fashion of bonding to Zn) only as the minor species was also observed in case of propene." @default.
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- W2315676964 date "2012-05-15" @default.
- W2315676964 modified "2023-09-24" @default.
- W2315676964 title "Structure of Allylic Intermediate on Zinc Oxide, π or σ?" @default.
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- W2315676964 doi "https://doi.org/10.1021/jp302060e" @default.
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