FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2315690014> ?p ?o ?g. }

• W2315690014 endingPage "7050" @default.
• W2315690014 startingPage "7041" @default.
• W2315690014 abstract "This article reports a robust method based upon polyol reduction for the deterministic synthesis of Pd decahedra or icosahedra with tunable sizes and a purity approaching 100%. The success of such a selective synthesis relies on an ability to fine-tune the reaction kinetics through the addition of Na2SO4 and HCl for decahedra and icosahedra, respectively. In the absence of any additive, the product of a similar synthesis in diethylene glycol contained 10% decahedra and 90% icosahedra. By optimizing the amount of Na2SO4 (or HCl) added into the reaction solution, the percent of decahedra (or icosahedra) in the product could be increased up to 100%. The roles of Na2SO4 and HCl were also investigated in great detail, and two plausible mechanisms were proposed and validated through a set of experiments. In general, a faster reduction rate is needed for the synthesis of Pd decahedra when compared with what is needed for Pd icosahedra. This work not only offers a simple approach to the deterministic syntheses of Pd decahedra and icosahedra but also provides an in-depth understanding of the mechanisms involved in shape-controlled syntheses of noble-metal nanocrystals from the perspective of reaction kinetics. On the basis of the mechanistic understanding, we have also achieved successful synthesis of Pd decahedra as pure samples by adding a proper amount of NaOH into the system to speed up the reduction kinetics." @default.
• W2315690014 created "2016-06-24" @default.
• W2315690014 creator A5008495864 @default.
• W2315690014 creator A5012672064 @default.
• W2315690014 creator A5015551041 @default.
• W2315690014 creator A5022403889 @default.
• W2315690014 creator A5041556229 @default.
• W2315690014 creator A5042134785 @default.
• W2315690014 creator A5048881523 @default.
• W2315690014 creator A5066788486 @default.
• W2315690014 creator A5074406656 @default.
• W2315690014 date "2014-07-07" @default.
• W2315690014 modified "2023-10-02" @default.
• W2315690014 title "Polyol Syntheses of Palladium Decahedra and Icosahedra as Pure Samples by Maneuvering the Reaction Kinetics with Additives" @default.
• W2315690014 cites W1964847069 @default.
• W2315690014 cites W1966419198 @default.
• W2315690014 cites W1970836873 @default.
• W2315690014 cites W1971212285 @default.
• W2315690014 cites W1972144600 @default.
• W2315690014 cites W1973453592 @default.
• W2315690014 cites W1979120033 @default.
• W2315690014 cites W1979742430 @default.
• W2315690014 cites W1980378453 @default.
• W2315690014 cites W1982161876 @default.
• W2315690014 cites W1988709622 @default.
• W2315690014 cites W1993323931 @default.
• W2315690014 cites W1993915865 @default.
• W2315690014 cites W1997304675 @default.
• W2315690014 cites W2001933696 @default.
• W2315690014 cites W2008996176 @default.
• W2315690014 cites W2015847862 @default.
• W2315690014 cites W2019801150 @default.
• W2315690014 cites W2022272458 @default.
• W2315690014 cites W2025450830 @default.
• W2315690014 cites W2028965666 @default.
• W2315690014 cites W2034797811 @default.
• W2315690014 cites W2038276266 @default.
• W2315690014 cites W2042169264 @default.
• W2315690014 cites W2059795417 @default.
• W2315690014 cites W2061815548 @default.
• W2315690014 cites W2063803818 @default.
• W2315690014 cites W2066384800 @default.
• W2315690014 cites W2068058707 @default.
• W2315690014 cites W2078878466 @default.
• W2315690014 cites W2081855029 @default.
• W2315690014 cites W2082349588 @default.
• W2315690014 cites W2089002247 @default.
• W2315690014 cites W2089340592 @default.
• W2315690014 cites W2092188508 @default.
• W2315690014 cites W2093853901 @default.
• W2315690014 cites W2093896534 @default.
• W2315690014 cites W2112305783 @default.
• W2315690014 cites W2116825123 @default.
• W2315690014 cites W2120640619 @default.
• W2315690014 cites W2122648820 @default.
• W2315690014 cites W2123013425 @default.
• W2315690014 cites W2125570899 @default.
• W2315690014 cites W2134921387 @default.
• W2315690014 cites W2139683943 @default.
• W2315690014 cites W2142574938 @default.
• W2315690014 cites W2152350263 @default.
• W2315690014 cites W2152911357 @default.
• W2315690014 cites W2154531412 @default.
• W2315690014 cites W2158712341 @default.
• W2315690014 cites W2160810567 @default.
• W2315690014 cites W2164557796 @default.
• W2315690014 cites W2164888426 @default.
• W2315690014 cites W2166766557 @default.
• W2315690014 cites W2168789419 @default.
• W2315690014 cites W2314003251 @default.
• W2315690014 cites W2314318713 @default.
• W2315690014 cites W2319932343 @default.
• W2315690014 cites W2319936148 @default.
• W2315690014 cites W2331608792 @default.
• W2315690014 cites W2333324640 @default.
• W2315690014 cites W2335066618 @default.
• W2315690014 doi "https://doi.org/10.1021/nn501919e" @default.
• W2315690014 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24988521" @default.
• W2315690014 hasPublicationYear "2014" @default.
• W2315690014 type Work @default.
• W2315690014 sameAs 2315690014 @default.
• W2315690014 citedByCount "90" @default.
• W2315690014 countsByYear W23156900142015 @default.
• W2315690014 countsByYear W23156900142016 @default.
• W2315690014 countsByYear W23156900142017 @default.
• W2315690014 countsByYear W23156900142018 @default.
• W2315690014 countsByYear W23156900142019 @default.
• W2315690014 countsByYear W23156900142020 @default.
• W2315690014 countsByYear W23156900142021 @default.
• W2315690014 countsByYear W23156900142022 @default.
• W2315690014 countsByYear W23156900142023 @default.
• W2315690014 crossrefType "journal-article" @default.
• W2315690014 hasAuthorship W2315690014A5008495864 @default.
• W2315690014 hasAuthorship W2315690014A5012672064 @default.
• W2315690014 hasAuthorship W2315690014A5015551041 @default.
• W2315690014 hasAuthorship W2315690014A5022403889 @default.
• W2315690014 hasAuthorship W2315690014A5041556229 @default.
• W2315690014 hasAuthorship W2315690014A5042134785 @default.

• next