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• W2315690865 endingPage "370" @default.
• W2315690865 startingPage "366" @default.
• W2315690865 abstract "There has been steady interest in the aqueous reaction of ClO2• with sulfur(IV) since the 1950s, and a wide variety of rate laws and mechanisms have been proposed. In neutral-to-alkaline media, the reaction is challenging to study because of its great rate. Here it is shown that benzaldehyde can be used as an additive to slow the reaction and make its rates more amenable to study. The rates can be quantitatively modeled by a mechanism that includes reversible binding of sulfur(IV) by benzaldehyde and a rate-limiting mixed second-order reaction of ClO2• with SO32–. The latter reaction occurs through parallel electron transfer from SO32– to ClO2• and oxygen-atom transfer from ClO2• to SO32–." @default.
• W2315690865 created "2016-06-24" @default.
• W2315690865 creator A5003081752 @default.
• W2315690865 creator A5056344103 @default.
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• W2315690865 date "2015-12-17" @default.
• W2315690865 modified "2023-10-18" @default.
• W2315690865 title "Kinetics of the Benzaldehyde-Inhibited Oxidation of Sulfite by Chlorine Dioxide" @default.
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• W2315690865 doi "https://doi.org/10.1021/acs.inorgchem.5b02770" @default.
• W2315690865 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26678913" @default.
• W2315690865 hasPublicationYear "2015" @default.
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