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- W2315692477 abstract "This work reports the hydrolysis of vegetable oils catalyzed by SO3H-functional Brønsted acidic ionic liquids at moderate hydrolysis temperature and reaction time. The results demonstrated that the catalytic activity of ionic liquids is in the sequence 1-(4-sulfonic group) butylcaprolactamium hydrogen sulfate ([HSO3-bCPL][HSO4]) > 1-(4-sulfonic group) butylpyridinium hydrogen sulfate ([HSO3-bPy][HSO4]) > 1-(4-sulfonic group) butyl-3-methylimidazolium hydrogen sulfate ([HSO3-bMIM][HSO4]) > 1-(4-sulfonic group) butyltriethylaminium hydrogen sulfate ([HSO3-bTEA][HSO4]). In the batch reactor, the reaction conditions of the hydrolysis in the presence of [HSO3-bCPL][HSO4] were investigated and optimized. The yield of fatty acids was greater than 95 wt % at [HSO3-bCPL][HSO4] dosage of 8 wt % (based on the weight of oil), water/oil molar ratio of 10:1, hydrolysis temperature of 180 °C, and hydrolysis time of 6 h. The catalytic performance of this ionic liquid remained excellent even after reuse six times." @default.
- W2315692477 created "2016-06-24" @default.
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- W2315692477 date "2014-07-15" @default.
- W2315692477 modified "2023-10-16" @default.
- W2315692477 title "Hydrolysis of Vegetable Oils to Fatty Acids Using Brønsted Acidic Ionic Liquids as Catalysts" @default.
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- W2315692477 doi "https://doi.org/10.1021/ie501524z" @default.
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