Matches in SemOpenAlex for { <https://semopenalex.org/work/W2315706100> ?p ?o ?g. }
- W2315706100 endingPage "7103" @default.
- W2315706100 startingPage "7096" @default.
- W2315706100 abstract "In present report, we explored hyperconjugation effects on the site- and bond-selective dissociation processes of cationic ethanol conformers by the use of theoretical methods (including configuration optimizations, natural bond orbital (NBO) analysis, and density of states (DOS) calculations, etc.) and the tunable synchrotron vacuum ultraviolet (SVUV) photoionization mass spectrometry. The dissociative mechanism of ethanol cations, in which hyperconjugative interactions and charge-transfer processes were involved, was proposed. The results reveal Cα–H and C–C bonds are selectively weakened, which arise as a result of the hyperconjugative interactions σCα-H → p in the trans-conformer and σC–C → p in gauche-conformer after being ionized. As a result, the selective bond cleavages would occur and different fragments were observed." @default.
- W2315706100 created "2016-06-24" @default.
- W2315706100 creator A5002874755 @default.
- W2315706100 creator A5009067661 @default.
- W2315706100 creator A5021850142 @default.
- W2315706100 creator A5072163238 @default.
- W2315706100 creator A5089535912 @default.
- W2315706100 date "2014-08-12" @default.
- W2315706100 modified "2023-10-12" @default.
- W2315706100 title "Site-Selective Dissociation Processes of Cationic Ethanol Conformers: The Role of Hyperconjugation" @default.
- W2315706100 cites W1574356778 @default.
- W2315706100 cites W1969455257 @default.
- W2315706100 cites W1997968609 @default.
- W2315706100 cites W2004650656 @default.
- W2315706100 cites W2004774498 @default.
- W2315706100 cites W2008125394 @default.
- W2315706100 cites W2009065986 @default.
- W2315706100 cites W2011743505 @default.
- W2315706100 cites W2017410926 @default.
- W2315706100 cites W2021798993 @default.
- W2315706100 cites W2024986500 @default.
- W2315706100 cites W2034158482 @default.
- W2315706100 cites W2036085011 @default.
- W2315706100 cites W2040238993 @default.
- W2315706100 cites W2040300491 @default.
- W2315706100 cites W2042570101 @default.
- W2315706100 cites W2042784471 @default.
- W2315706100 cites W2046482191 @default.
- W2315706100 cites W2049275209 @default.
- W2315706100 cites W2055757471 @default.
- W2315706100 cites W2064805874 @default.
- W2315706100 cites W2066103357 @default.
- W2315706100 cites W2072291795 @default.
- W2315706100 cites W2078556536 @default.
- W2315706100 cites W2083809255 @default.
- W2315706100 cites W2085336624 @default.
- W2315706100 cites W2086803729 @default.
- W2315706100 cites W2114030802 @default.
- W2315706100 cites W2132525235 @default.
- W2315706100 cites W2137115814 @default.
- W2315706100 cites W2171529240 @default.
- W2315706100 cites W2325608039 @default.
- W2315706100 cites W2335548734 @default.
- W2315706100 cites W2950594559 @default.
- W2315706100 cites W4247925199 @default.
- W2315706100 doi "https://doi.org/10.1021/jp5035568" @default.
- W2315706100 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25080068" @default.
- W2315706100 hasPublicationYear "2014" @default.
- W2315706100 type Work @default.
- W2315706100 sameAs 2315706100 @default.
- W2315706100 citedByCount "0" @default.
- W2315706100 crossrefType "journal-article" @default.
- W2315706100 hasAuthorship W2315706100A5002874755 @default.
- W2315706100 hasAuthorship W2315706100A5009067661 @default.
- W2315706100 hasAuthorship W2315706100A5021850142 @default.
- W2315706100 hasAuthorship W2315706100A5072163238 @default.
- W2315706100 hasAuthorship W2315706100A5089535912 @default.
- W2315706100 hasConcept C102931765 @default.
- W2315706100 hasConcept C130188946 @default.
- W2315706100 hasConcept C144557053 @default.
- W2315706100 hasConcept C145148216 @default.
- W2315706100 hasConcept C147597530 @default.
- W2315706100 hasConcept C147789679 @default.
- W2315706100 hasConcept C152365726 @default.
- W2315706100 hasConcept C158749347 @default.
- W2315706100 hasConcept C177186529 @default.
- W2315706100 hasConcept C178790620 @default.
- W2315706100 hasConcept C183882617 @default.
- W2315706100 hasConcept C185592680 @default.
- W2315706100 hasConcept C18705241 @default.
- W2315706100 hasConcept C198291218 @default.
- W2315706100 hasConcept C32909587 @default.
- W2315706100 hasConcept C75473681 @default.
- W2315706100 hasConceptScore W2315706100C102931765 @default.
- W2315706100 hasConceptScore W2315706100C130188946 @default.
- W2315706100 hasConceptScore W2315706100C144557053 @default.
- W2315706100 hasConceptScore W2315706100C145148216 @default.
- W2315706100 hasConceptScore W2315706100C147597530 @default.
- W2315706100 hasConceptScore W2315706100C147789679 @default.
- W2315706100 hasConceptScore W2315706100C152365726 @default.
- W2315706100 hasConceptScore W2315706100C158749347 @default.
- W2315706100 hasConceptScore W2315706100C177186529 @default.
- W2315706100 hasConceptScore W2315706100C178790620 @default.
- W2315706100 hasConceptScore W2315706100C183882617 @default.
- W2315706100 hasConceptScore W2315706100C185592680 @default.
- W2315706100 hasConceptScore W2315706100C18705241 @default.
- W2315706100 hasConceptScore W2315706100C198291218 @default.
- W2315706100 hasConceptScore W2315706100C32909587 @default.
- W2315706100 hasConceptScore W2315706100C75473681 @default.
- W2315706100 hasFunder F4320321001 @default.
- W2315706100 hasFunder F4320321921 @default.
- W2315706100 hasIssue "34" @default.
- W2315706100 hasLocation W23157061001 @default.
- W2315706100 hasLocation W23157061002 @default.
- W2315706100 hasOpenAccess W2315706100 @default.
- W2315706100 hasPrimaryLocation W23157061001 @default.
- W2315706100 hasRelatedWork W1988371098 @default.
- W2315706100 hasRelatedWork W2013495482 @default.