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- W2315744437 abstract "Chiral iron alkyl and iron alkoxide complexes bearing boxmi pincers as stereodirecting ligands have been employed as catalysts for enantioselective hydrosilylation reactions with unprecedented activity and selectivity (TOF = 240 h–1 at −40 °C, ee up to 99% for alkyl aryl ketones), which match the performance of previously established noble-metal-based catalysts. This shows the potential of earth-abundant metals such as iron for replacing platinum—metals without any drawbacks for the reaction design." @default.
- W2315744437 created "2016-06-24" @default.
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- W2315744437 date "2015-02-13" @default.
- W2315744437 modified "2023-10-18" @default.
- W2315744437 title "Iron Achieves Noble Metal Reactivity and Selectivity: Highly Reactive and Enantioselective Iron Complexes as Catalysts in the Hydrosilylation of Ketones" @default.
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- W2315744437 doi "https://doi.org/10.1021/ja512986m" @default.
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