FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2315823218> ?p ?o ?g. }

• W2315823218 endingPage "6043" @default.
• W2315823218 startingPage "6034" @default.
• W2315823218 abstract "The [MoCu] carbon monoxide dehydrogenase (CODH) is a Cu-containing molybdo-flavoprotein, the active site of which contains a pterin-dithiolene cofactor bound to a sulfido-bridged dinuclear Mo−Cu complex. In this paper, the synthesis and characterization of dinuclear Mo−Cu complexes relevant to the active site of [MoCu]-CODH are described. Reaction of [MoO2S2]2- with CuCN affords the dinuclear complex [O2MoS2Cu(CN)]2- (1), in which the CN- ligand can be replaced with various aryl thiolates to give rise to a series of dinuclear complexes [O2MoS2Cu(SAr)]2- (Ar = Ph (2), o-Tol (3), and p-Tol (4)). An alternative synthesis of complex 2 is the reaction of [MoO2S2]2- with [Cu(SPh)3]2-. Similarly, [O2MoS2Cu(PPh3)]- (5), [O2MoS2Cu(dppe)]- (dppe = 1,2-bis(diphenylphosphino)ethane) (6), and [O2MoS2Cu(triphos)]- (triphos = 1,1,1-tris[(diphenylphosphino)methyl]ethane) (7) were prepared from the reactions of [MoO2S2]2- with the Cu(I) phosphine complexes. Treatment of 1, 2, 4, or 5 with dithiols (1,2-(SH)2C6H4, 1,2-(SH)2C6H2-3,6-Cl2, and 1,2-(SH)2C2H4), in acetonitrile, leads to the replacement of a molybdenum-bound oxo ligand to yield [(dithiolate)Mo(O)S2CuL]2- (L = CN, SAr; dithiolate = 1,2-S2C6H4, 1,2-S2C6H2-3,6-Cl2, or 1,2-S2C2H4) (8−13) or [(1,2-S2C6H4)Mo(O)S2Cu(PPh3)]- (14) complexes." @default.
• W2315823218 created "2016-06-24" @default.
• W2315823218 creator A5025983349 @default.
• W2315823218 creator A5060292429 @default.
• W2315823218 creator A5061652895 @default.
• W2315823218 date "2005-07-29" @default.
• W2315823218 modified "2023-09-29" @default.
• W2315823218 title "Sulfido-Bridged Dinuclear Molybdenum−Copper Complexes Related to the Active Site of CO Dehydrogenase: [(dithiolate)Mo(O)S₂Cu(SAr)]²^- (dithiolate = 1,2-S₂C₆H₄, 1,2-S₂C₆H₂-3,6-Cl₂, 1,2-S₂C₂H₄)" @default.
• W2315823218 cites W1963899632 @default.
• W2315823218 cites W1971083387 @default.
• W2315823218 cites W1971754594 @default.
• W2315823218 cites W1971986379 @default.
• W2315823218 cites W1973458202 @default.
• W2315823218 cites W1973566511 @default.
• W2315823218 cites W1981605898 @default.
• W2315823218 cites W1982974869 @default.
• W2315823218 cites W1989431920 @default.
• W2315823218 cites W1991180369 @default.
• W2315823218 cites W1992425436 @default.
• W2315823218 cites W1992666035 @default.
• W2315823218 cites W1999451494 @default.
• W2315823218 cites W2002031079 @default.
• W2315823218 cites W2005447108 @default.
• W2315823218 cites W2006199697 @default.
• W2315823218 cites W2006243394 @default.
• W2315823218 cites W2022081593 @default.
• W2315823218 cites W2022379622 @default.
• W2315823218 cites W2025957631 @default.
• W2315823218 cites W2033965639 @default.
• W2315823218 cites W2035932930 @default.
• W2315823218 cites W2042795760 @default.
• W2315823218 cites W2045356208 @default.
• W2315823218 cites W2048389524 @default.
• W2315823218 cites W2048642998 @default.
• W2315823218 cites W2068237497 @default.
• W2315823218 cites W2069893237 @default.
• W2315823218 cites W2077689461 @default.
• W2315823218 cites W2081260989 @default.
• W2315823218 cites W2081405532 @default.
• W2315823218 cites W2086832398 @default.
• W2315823218 cites W2091853033 @default.
• W2315823218 cites W2092618008 @default.
• W2315823218 cites W2117206348 @default.
• W2315823218 cites W2145218680 @default.
• W2315823218 cites W2145818582 @default.
• W2315823218 cites W2330949886 @default.
• W2315823218 cites W2331918425 @default.
• W2315823218 cites W2952761781 @default.
• W2315823218 cites W3138961949 @default.
• W2315823218 cites W4245399940 @default.
• W2315823218 doi "https://doi.org/10.1021/ic050294v" @default.
• W2315823218 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16097823" @default.
• W2315823218 hasPublicationYear "2005" @default.
• W2315823218 type Work @default.
• W2315823218 sameAs 2315823218 @default.
• W2315823218 citedByCount "53" @default.
• W2315823218 countsByYear W23158232182012 @default.
• W2315823218 countsByYear W23158232182013 @default.
• W2315823218 countsByYear W23158232182014 @default.
• W2315823218 countsByYear W23158232182015 @default.
• W2315823218 countsByYear W23158232182016 @default.
• W2315823218 countsByYear W23158232182017 @default.
• W2315823218 countsByYear W23158232182018 @default.
• W2315823218 countsByYear W23158232182019 @default.
• W2315823218 countsByYear W23158232182020 @default.
• W2315823218 countsByYear W23158232182021 @default.
• W2315823218 countsByYear W23158232182022 @default.
• W2315823218 countsByYear W23158232182023 @default.
• W2315823218 crossrefType "journal-article" @default.
• W2315823218 hasAuthorship W2315823218A5025983349 @default.
• W2315823218 hasAuthorship W2315823218A5060292429 @default.
• W2315823218 hasAuthorship W2315823218A5061652895 @default.
• W2315823218 hasConcept C116569031 @default.
• W2315823218 hasConcept C134121241 @default.
• W2315823218 hasConcept C155647269 @default.
• W2315823218 hasConcept C161790260 @default.
• W2315823218 hasConcept C170493617 @default.
• W2315823218 hasConcept C178790620 @default.
• W2315823218 hasConcept C179104552 @default.
• W2315823218 hasConcept C185592680 @default.
• W2315823218 hasConcept C191897082 @default.
• W2315823218 hasConcept C192562407 @default.
• W2315823218 hasConcept C2777463227 @default.
• W2315823218 hasConcept C2777716191 @default.
• W2315823218 hasConcept C2778186837 @default.
• W2315823218 hasConcept C2780049555 @default.
• W2315823218 hasConcept C2780263894 @default.
• W2315823218 hasConcept C2781076698 @default.
• W2315823218 hasConcept C32909587 @default.
• W2315823218 hasConcept C41183919 @default.
• W2315823218 hasConcept C512735826 @default.
• W2315823218 hasConcept C549387045 @default.
• W2315823218 hasConcept C55493867 @default.
• W2315823218 hasConcept C71240020 @default.
• W2315823218 hasConcept C8010536 @default.
• W2315823218 hasConceptScore W2315823218C116569031 @default.
• W2315823218 hasConceptScore W2315823218C134121241 @default.
• W2315823218 hasConceptScore W2315823218C155647269 @default.

• next