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• W2315910656 abstract "An advanced strategy for efficient macrocyclic Cu(I)-catalyzed cycloaddition is described. The key features include employing azide–iodoalkyne cycloadditions (CuAiAC), low catalyst loadings, relatively high concentrations (30 mM → 300 mM), and application to continuous flow. The remarkably efficient new tool affords a variety of macrocyclic skeletons having either different alkyl, aryl, or amino acid spacers in high yields (70–97%). The macrocyclic CuAiAC process affords macrocycles having an iodotriazole moiety that can be further functionalized using standard Pd-catalyzed cross-couplings." @default.
• W2315910656 created "2016-06-24" @default.
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• W2315910656 date "2014-09-29" @default.
• W2315910656 modified "2023-10-17" @default.
• W2315910656 title "Advanced Strategies for Efficient Macrocyclic Cu(I)-Catalyzed Cycloaddition of Azides" @default.
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• W2315910656 doi "https://doi.org/10.1021/ol502415a" @default.
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