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- W2315927667 abstract "There are two types of shift of absorption spectrum at surfactant concentrations above the citical micelle concentration, one is the system shifting to a longer wavelenth side (red shift; alkylparaben-sodium dodecyl sulfate (SDS) solution system, alkyl gallate-cetyl trimethylammonium bromide (CTAB) solution system, etc.) and the other is the system shifting to a shorter wavelength side (blue shift; sorbic acid-SDS solution system, benzoic acid-CTAB solution system, etc.). The distribution parameter values can be obtained through measuring the shift-length of the maximum absorption wavelength by the first derivative absorption spectrum (FDAS-SL method), regardless of their shift direction.It was confirmed that in a case where discrimination by the absorption spectrum of drugs is difficults (for example, alkylparabens), measurement of the distribution parameter values is a good alternative. In the case of alkylparabens, discrimination was easily attained in the order of SDS (anionic)>CTAB (cationic)>octaethylene glycol monododecyl ether>polyoxyethylene (20) sorbitan monolaurate (nonionic) solution. Room temperature was the best condition for the measurement." @default.
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- W2315927667 date "1991-01-01" @default.
- W2315927667 modified "2023-10-16" @default.
- W2315927667 title "Measurement of the Distribution Parameter in Solubilized Systems. III. Measurement of the Distribution Parameter of Drugs Which Show Blue or Red Shifts in the Surfactant Solution and Its Utilization for Discrimination." @default.
- W2315927667 doi "https://doi.org/10.1248/cpb.39.2750" @default.
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