FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2315980277> ?p ?o ?g. }

• W2315980277 endingPage "27306" @default.
• W2315980277 startingPage "27298" @default.
• W2315980277 abstract "We study the temperature-dependent molecular dynamics, ion conduction, and phase behavior of plastic-crystal electrolytes based on the succinonitrile molecule. We employ calorimetry and dielectric spectroscopy to probe binary mixtures of succinonitrile with glutaronitrile or acetonitrile and also analyze the effect of dissolving lithium salts in these systems. The glutaronitrile–succinonitrile mixture has the highest conductivity, and it is the only plastic-crystal system that displays a perfect correlation between the ion drift and the on-site reorientational dynamics. Doping with lithium ions boosts the conductivity but breaks such perfect correlation. All of these features can be rationalized by assuming that conduction is due to the self-diffusion of a minority of ionized dinitrile molecules. Doping with lithium salts slows down the collective molecular dynamics while leaving the intramolecular relaxation motion unaffected. All samples exhibit a very broad melting transition and exist in a mixed liquid plus plastic state near room temperature. Some mixtures undergo phase segregation below 233 K, the transition temperature between the plastic and the fully ordered solid phase in pure succinonitrile, resulting in the appearance of a space-charge relaxation loss. Phase separation therefore plays an important role in pristine and lithium-doped succinonitrile mixtures." @default.
• W2315980277 created "2016-06-24" @default.
• W2315980277 creator A5001275678 @default.
• W2315980277 creator A5044972268 @default.
• W2315980277 creator A5051463639 @default.
• W2315980277 creator A5053139423 @default.
• W2315980277 creator A5064139616 @default.
• W2315980277 creator A5086029133 @default.
• W2315980277 date "2015-11-23" @default.
• W2315980277 modified "2023-10-16" @default.
• W2315980277 title "Self-Diffusion, Phase Behavior, and Li⁺ Ion Conduction in Succinonitrile-Based Plastic Cocrystals" @default.
• W2315980277 cites W1532410410 @default.
• W2315980277 cites W1876945131 @default.
• W2315980277 cites W1963743200 @default.
• W2315980277 cites W1966705363 @default.
• W2315980277 cites W1969426426 @default.
• W2315980277 cites W1977124944 @default.
• W2315980277 cites W1984480486 @default.
• W2315980277 cites W1984569119 @default.
• W2315980277 cites W1988042929 @default.
• W2315980277 cites W1989278133 @default.
• W2315980277 cites W1992345572 @default.
• W2315980277 cites W1993378049 @default.
• W2315980277 cites W2000291560 @default.
• W2315980277 cites W2003011764 @default.
• W2315980277 cites W2004291123 @default.
• W2315980277 cites W2004600813 @default.
• W2315980277 cites W2011630845 @default.
• W2315980277 cites W2018695590 @default.
• W2315980277 cites W2024095048 @default.
• W2315980277 cites W2024202752 @default.
• W2315980277 cites W2029835312 @default.
• W2315980277 cites W2034238760 @default.
• W2315980277 cites W2037400387 @default.
• W2315980277 cites W2042188843 @default.
• W2315980277 cites W2045137012 @default.
• W2315980277 cites W2047061717 @default.
• W2315980277 cites W2059917036 @default.
• W2315980277 cites W2065505570 @default.
• W2315980277 cites W2066157141 @default.
• W2315980277 cites W2074920486 @default.
• W2315980277 cites W2076659739 @default.
• W2315980277 cites W2077025851 @default.
• W2315980277 cites W2085909856 @default.
• W2315980277 cites W2090176806 @default.
• W2315980277 cites W2112299033 @default.
• W2315980277 cites W2131812039 @default.
• W2315980277 cites W2191478886 @default.
• W2315980277 cites W2328713354 @default.
• W2315980277 cites W3101108708 @default.
• W2315980277 cites W3104575263 @default.
• W2315980277 cites W4244317435 @default.
• W2315980277 cites W585924654 @default.
• W2315980277 doi "https://doi.org/10.1021/acs.jpcc.5b09380" @default.
• W2315980277 hasPublicationYear "2015" @default.
• W2315980277 type Work @default.
• W2315980277 sameAs 2315980277 @default.
• W2315980277 citedByCount "28" @default.
• W2315980277 countsByYear W23159802772016 @default.
• W2315980277 countsByYear W23159802772017 @default.
• W2315980277 countsByYear W23159802772018 @default.
• W2315980277 countsByYear W23159802772019 @default.
• W2315980277 countsByYear W23159802772020 @default.
• W2315980277 countsByYear W23159802772021 @default.
• W2315980277 countsByYear W23159802772022 @default.
• W2315980277 countsByYear W23159802772023 @default.
• W2315980277 crossrefType "journal-article" @default.
• W2315980277 hasAuthorship W2315980277A5001275678 @default.
• W2315980277 hasAuthorship W2315980277A5044972268 @default.
• W2315980277 hasAuthorship W2315980277A5051463639 @default.
• W2315980277 hasAuthorship W2315980277A5053139423 @default.
• W2315980277 hasAuthorship W2315980277A5064139616 @default.
• W2315980277 hasAuthorship W2315980277A5086029133 @default.
• W2315980277 hasBestOaLocation W23159802771 @default.
• W2315980277 hasConcept C113196181 @default.
• W2315980277 hasConcept C121332964 @default.
• W2315980277 hasConcept C131540310 @default.
• W2315980277 hasConcept C134018914 @default.
• W2315980277 hasConcept C138679309 @default.
• W2315980277 hasConcept C145148216 @default.
• W2315980277 hasConcept C147789679 @default.
• W2315980277 hasConcept C149288129 @default.
• W2315980277 hasConcept C15744967 @default.
• W2315980277 hasConcept C159467904 @default.
• W2315980277 hasConcept C17525397 @default.
• W2315980277 hasConcept C178790620 @default.
• W2315980277 hasConcept C185592680 @default.
• W2315980277 hasConcept C192562407 @default.
• W2315980277 hasConcept C2776029896 @default.
• W2315980277 hasConcept C2778541603 @default.
• W2315980277 hasConcept C2780958456 @default.
• W2315980277 hasConcept C2781161615 @default.
• W2315980277 hasConcept C44280652 @default.
• W2315980277 hasConcept C68801617 @default.
• W2315980277 hasConcept C69357855 @default.
• W2315980277 hasConcept C71924100 @default.
• W2315980277 hasConcept C77805123 @default.
• W2315980277 hasConcept C97355855 @default.

• next