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- W2316013753 abstract "A series of arene ruthenium architectures have been prepared from coordination-driven self-assembly using dinuclear p-cymene ruthenium acceptors and π-donating tetratopic tetrapyridyl–tetrathiafulvalene donor ligands. The synthetic strategy, based on a geometric interaction approach, leads to four electroactive metalla-assemblies, 1–4 (one molecular cube and three metallaplates), that were characterized by NMR, ESI-MS, X-ray diffraction, and cyclic voltammetry. Rationalization of their formation discrepancy was completed by DFT calculations supported by structural features of their constituting TTF and Ru-complex components. Metalla-architectures possessing electron-rich cores (3, cis-4, and trans-4) interact strongly with picric acid (PA) to yield cocrystallized products, PA + metalla-assemblies, confirmed by single-crystal X-ray structure analyses." @default.
- W2316013753 created "2016-06-24" @default.
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- W2316013753 date "2014-03-27" @default.
- W2316013753 modified "2023-10-18" @default.
- W2316013753 title "Electron-Rich Arene–Ruthenium Metalla-architectures Incorporating Tetrapyridyl–Tetrathiafulvene Donor Moieties" @default.
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- W2316013753 doi "https://doi.org/10.1021/om401142j" @default.
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