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- W2316014047 abstract "Highly selective tail-to-tail dimerization of methyl methacrylate has been realized by an N-heterocyclic carbene catalyst, giving dimethyl 2,5-dimethyl-2-hexenedioate with an E/Z ratio of 95:5 in 86% isolated yield. The umpolung mechanism is proposed on the basis of interception of the intermediates using ESI-MS analyses and deuterium-labeling experiments." @default.
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- W2316014047 date "2011-06-23" @default.
- W2316014047 modified "2023-10-12" @default.
- W2316014047 title "Organocatalytic Tail-to-Tail Dimerization of Olefin: Umpolung of Methyl Methacrylate Mediated by N-Heterocyclic Carbene" @default.
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- W2316014047 doi "https://doi.org/10.1021/ol201380m" @default.
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