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- W2316082812 abstract "The design of a biphasic system is important for the development of liquid–liquid extraction and biphasic catalysis. In this work, we report a series of ternary biphasic systems that consist of hydrophilic ionic liquid (IL), water, and ethyl acetate. The effects of the structure of the ILs (cation, anion, and substituent group), IL/water ratio, and temperature on the phase equilibrium of these biphasic systems were investigated. The mutual solubility was lower in the IL/water–ethyl acetate biphasic system than in the water–ethyl acetate system when ILs with strong hydration ability were introduced, such as [EMIm]OAc, [EMIm]Cl, [EMIm]NO3, [EMIm]EtSO4, and [HOEMIm]Cl. In addition, the hydrogen-bonding basicity of the IL-containing phase could be tuned by changing the IL structure or IL/water ratio. These novel IL/water-ethyl acetate biphasic systems may present another option in addition to hydrophobic IL–water and aqueous biphasic systems for liquid–liquid extraction." @default.
- W2316082812 created "2016-06-24" @default.
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- W2316082812 date "2014-06-18" @default.
- W2316082812 modified "2023-10-17" @default.
- W2316082812 title "Biphasic Systems That Consist of Hydrophilic Ionic Liquid, Water, and Ethyl Acetate: The Effects of Interactions on the Phase Behavior" @default.
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- W2316082812 doi "https://doi.org/10.1021/ie5007273" @default.
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