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• W2316114259 startingPage "7294" @default.
• W2316114259 abstract "PtM (M = Ni, Fe, Co) alloy nanoparticles were synthesized by a liquid phase reduction method employing butyllithium as a reducing agent. The alumina-supported PtM materials were then used as precursors to obtain the Pt-MxOy/Al2O3 catalysts through calcination. The influence of synthesis conditions of PtM alloy nanoparticles and the catalytic performance of the Pt-MxOy/Al2O3 catalysts for p-chloronitrobenzene hydrogenation reaction were investigated. The relevant characterizations such as XRD, XPS, and TEM were conducted for PtM alloy nanoparticles and Pt-MxOy/Al2O3 catalysts, and the result showed that the PtM nanoparticles are uniform alloy. Moreover, compared to PtM alloy nanoparticles, the Pt particle size of Pt-MxOy/Al2O3 using PtM alloy nanoparticle precursors did not increase by calcination, indicating good thermal stability. The catalytic activities of Pt-MxOy/Al2O3 for p-chloronitrobenzene hydrogenation reaction were significantly higher than that of control Pt/Al2O3 catalysts due to its strong Pt-MxOy interaction." @default.
• W2316114259 created "2016-06-24" @default.
• W2316114259 creator A5027077382 @default.
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• W2316114259 date "2013-04-02" @default.
• W2316114259 modified "2023-10-02" @default.
• W2316114259 title "Enhanced Catalytic Hydrogenation Activity and Selectivity of Pt-M_<i>x</i>O_<i>y</i>/Al₂O₃ (M = Ni, Fe, Co) Heteroaggregate Catalysts by <i>in Situ</i> Transformation of PtM Alloy Nanoparticles" @default.
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• W2316114259 doi "https://doi.org/10.1021/jp309548v" @default.
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