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- W2316145462 abstract "The coupling reaction of 1,2-epoxy-4-cyclohexene with CO2 in the presence of a ZnCl2/nBu4NI catalyst system was shown to provide the naturally occurring cis-cyclohexadiene carbonate. An alternative synthesis of this compound, which was characterized by X-ray structural analysis, was carried out from the cis-diol and triphosgene. Upon utilizing binary or bifunctional (salen)CrX catalysts, this coupling process resulted in the selective formation of completely alternating copolymer of 1,2-epoxy-4-cyclohexene and carbon dioxide. In the case involving the binary chromium(III)/onium salt catalyst, small quantities of both the cis and trans cyclic carbonates were also produced. The (salen)CoDNP/PPNDNP (DNP = 2,4-dinitrophenolate) catalyst system was most effective at producing high molecular weight copolymer with 100% selectivity. The Tg of this polymer (Mn = 35.9 kDa) was determined to be 123 °C, which is higher than the Tg (116 °C) of the corresponding saturated copolymer. Depolymerization of poly(cyclohexadi..." @default.
- W2316145462 created "2016-06-24" @default.
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- W2316145462 date "2014-10-23" @default.
- W2316145462 modified "2023-09-25" @default.
- W2316145462 title "Copolymerization and Cycloaddition Products Derived from Coupling Reactions of 1,2-Epoxy-4-cyclohexene and Carbon Dioxide. Postpolymerization Functionalization via Thiol–Ene Click Reactions" @default.
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- W2316145462 doi "https://doi.org/10.1021/ma501781k" @default.
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