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• W2316147577 startingPage "2462" @default.
• W2316147577 abstract "The nitrogen transformation during the oxy-fuel combustion of coal and biomass mixtures was studied through thermogravimetry–mass spectrometry (TG–MS). Influence factors, such as atmosphere and biomass share, were selected to study the release of four nitrogenous gases HCN, HNCO, NH3, and NO. With the presence of ≥20% O2, the combustion of Datong coal and biomass mixtures releases less HCN, NH3, and NO and more HNCO in the O2/CO2 atmosphere compared to the O2/N2 atmosphere. HCN and HNCO compete mutually during the formation of nitrogenous gases. The mixtures of Datong coal and biomass release more nitrogenous gases than Datong coal alone in both O2/CO2 and O2/N2 atmospheres during the devolatilization. With the O2 concentration in the O2/CO2 atmosphere increasing from 20 to 100%, the relative yields of NH3, HCN, and HNCO produced from the mixtures decrease, while the NO yield increases. The HNCO yield changes greatly with the increase of the O2 concentration because of the oxidation by OH. Increasing the biomass share in the mixtures improves the relative yields of nitrogenous gases. The biomass share can greatly affect the HCN and HNCO yields, owing to the different forms of N-containing structures between coal and biomass." @default.
• W2316147577 created "2016-06-24" @default.
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• W2316147577 date "2015-03-16" @default.
• W2316147577 modified "2023-10-13" @default.
• W2316147577 title "Thermogravimetry–Mass Spectrometry Analysis of Nitrogen Transformation during Oxy-fuel Combustion of Coal and Biomass Mixtures" @default.
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• W2316147577 doi "https://doi.org/10.1021/acs.energyfuels.5b00019" @default.
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