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- W2316163838 endingPage "1607" @default.
- W2316163838 startingPage "1604" @default.
- W2316163838 abstract "Oxidative cyclization of tetrafluoroethylene (TFE) and ethylene with Ni(0) resulted in the formation of a five-membered nickelacycle. In the presence of PPh3 as an auxiliary ligand, the partially fluorinated five-membered nickelacycle was isolated and the structure was determined by X-ray analysis. This nickelacycle was found not only to react stoichiometrically with enones to give a cross-trimerization product but also to be a key reaction intermediate in the Ni(0)-catalyzed cotrimerization of TFE and ethylene, leading to 5,5,6,6-tetrafluoro-1-hexene." @default.
- W2316163838 created "2016-06-24" @default.
- W2316163838 creator A5026818519 @default.
- W2316163838 creator A5047304455 @default.
- W2316163838 creator A5069821285 @default.
- W2316163838 creator A5086183992 @default.
- W2316163838 date "2015-04-30" @default.
- W2316163838 modified "2023-10-12" @default.
- W2316163838 title "2,2,3,3-Tetrafluoronickelacyclopentanes Generated via the Oxidative Cyclization of Tetrafluoroethylene and Simple Alkenes: A Key Intermediate in Nickel-Catalyzed C–C Bond-Forming Reactions" @default.
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- W2316163838 doi "https://doi.org/10.1021/acs.organomet.5b00218" @default.
- W2316163838 hasPublicationYear "2015" @default.
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