Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316184297> ?p ?o ?g. }
- W2316184297 endingPage "1998" @default.
- W2316184297 startingPage "1991" @default.
- W2316184297 abstract "Reported herein is the excellent example of regio-/stereoselective coordination copolymerization of propylene with p-(3-butenyl)styrene (BSt) which produces exclusively high molecular weight (Mw > 50 × 103) isotactic polypropylenes (iPPs) with abundant ethenylbenzene (styrene) groups (>5 mol %) by use of non-metallocene catalyst. The current (pyridylamido)Hf/[Ph3C][B(C6F5)4]/AliBu3 system, which exhibits overwhelmingly favorable reactivity toward α-olefin over styrene moieties, effectively promoted the copolymerization of propylene with BSt under judiciously chosen reaction conditions, in which catalytic activity (1.35 kg polymer/(mmolHf h), molecular weight (Mw = 102 × 103), styrene group content (8.31 mol %), and tacticity ([mmmm] > 99%) reached a satisfying level simultaneously for the first time. Side group functionalized iPPs were synthesized in an almost quantitative way via the UV-light-initiated thiol–ene click chemistry and iodine-catalyzed hydroalkylation reaction of the resultant propylene/BSt copolymer with commercially available materials, demonstrating that the propylene copolymers containing abundant pendant styrene groups are excellent reactive intermediates for the preparation of various functional iPP materials." @default.
- W2316184297 created "2016-06-24" @default.
- W2316184297 creator A5007747867 @default.
- W2316184297 creator A5039832836 @default.
- W2316184297 creator A5073006756 @default.
- W2316184297 creator A5075403529 @default.
- W2316184297 date "2015-04-01" @default.
- W2316184297 modified "2023-10-18" @default.
- W2316184297 title "Convenient Syntheses and Versatile Functionalizations of Isotactic Polypropylene Containing Plentiful Pendant Styrene Groups with High Efficiency" @default.
- W2316184297 cites W1964034280 @default.
- W2316184297 cites W1964293471 @default.
- W2316184297 cites W1972528501 @default.
- W2316184297 cites W1973455511 @default.
- W2316184297 cites W1975532126 @default.
- W2316184297 cites W1975781601 @default.
- W2316184297 cites W1976814922 @default.
- W2316184297 cites W1977110020 @default.
- W2316184297 cites W1978487642 @default.
- W2316184297 cites W1978985250 @default.
- W2316184297 cites W1979519445 @default.
- W2316184297 cites W1982411449 @default.
- W2316184297 cites W1984081100 @default.
- W2316184297 cites W1984349413 @default.
- W2316184297 cites W1984467126 @default.
- W2316184297 cites W1986255608 @default.
- W2316184297 cites W1987855375 @default.
- W2316184297 cites W1989530681 @default.
- W2316184297 cites W2003433412 @default.
- W2316184297 cites W2012723429 @default.
- W2316184297 cites W2016083319 @default.
- W2316184297 cites W2018503776 @default.
- W2316184297 cites W2023549615 @default.
- W2316184297 cites W2024395848 @default.
- W2316184297 cites W2030753494 @default.
- W2316184297 cites W2031975829 @default.
- W2316184297 cites W2035438145 @default.
- W2316184297 cites W2044075587 @default.
- W2316184297 cites W2049448188 @default.
- W2316184297 cites W2049598180 @default.
- W2316184297 cites W2052209048 @default.
- W2316184297 cites W2054384160 @default.
- W2316184297 cites W2059140740 @default.
- W2316184297 cites W2059692007 @default.
- W2316184297 cites W2067536855 @default.
- W2316184297 cites W2069551259 @default.
- W2316184297 cites W2075755944 @default.
- W2316184297 cites W2076700493 @default.
- W2316184297 cites W2078468924 @default.
- W2316184297 cites W2080901625 @default.
- W2316184297 cites W2082150665 @default.
- W2316184297 cites W2087441324 @default.
- W2316184297 cites W2094783956 @default.
- W2316184297 cites W2111568088 @default.
- W2316184297 cites W2121632477 @default.
- W2316184297 cites W2122238952 @default.
- W2316184297 cites W2135140882 @default.
- W2316184297 cites W2137504609 @default.
- W2316184297 cites W2153375279 @default.
- W2316184297 cites W2158713123 @default.
- W2316184297 cites W2165645126 @default.
- W2316184297 cites W2166537855 @default.
- W2316184297 cites W2170904994 @default.
- W2316184297 cites W2315423254 @default.
- W2316184297 cites W2319643544 @default.
- W2316184297 cites W2320125855 @default.
- W2316184297 cites W2320679442 @default.
- W2316184297 cites W2327334331 @default.
- W2316184297 cites W2331059225 @default.
- W2316184297 cites W2331645888 @default.
- W2316184297 cites W2952693012 @default.
- W2316184297 cites W408371293 @default.
- W2316184297 cites W4250155229 @default.
- W2316184297 doi "https://doi.org/10.1021/acs.macromol.5b00128" @default.
- W2316184297 hasPublicationYear "2015" @default.
- W2316184297 type Work @default.
- W2316184297 sameAs 2316184297 @default.
- W2316184297 citedByCount "38" @default.
- W2316184297 countsByYear W23161842972016 @default.
- W2316184297 countsByYear W23161842972017 @default.
- W2316184297 countsByYear W23161842972018 @default.
- W2316184297 countsByYear W23161842972019 @default.
- W2316184297 countsByYear W23161842972020 @default.
- W2316184297 countsByYear W23161842972021 @default.
- W2316184297 countsByYear W23161842972022 @default.
- W2316184297 crossrefType "journal-article" @default.
- W2316184297 hasAuthorship W2316184297A5007747867 @default.
- W2316184297 hasAuthorship W2316184297A5039832836 @default.
- W2316184297 hasAuthorship W2316184297A5073006756 @default.
- W2316184297 hasAuthorship W2316184297A5075403529 @default.
- W2316184297 hasConcept C142724271 @default.
- W2316184297 hasConcept C15920480 @default.
- W2316184297 hasConcept C161790260 @default.
- W2316184297 hasConcept C178790620 @default.
- W2316184297 hasConcept C185592680 @default.
- W2316184297 hasConcept C188027245 @default.
- W2316184297 hasConcept C192562407 @default.
- W2316184297 hasConcept C204787440 @default.
- W2316184297 hasConcept C2776910235 @default.