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• W2316188056 abstract "Abstract The Al Mn alloy system contains complex intermetallics in its Al-rich part, and this was the first system where quasiperiodic structures were recognized. In the present work, the solubility of TMs (TM = Fe, Co, Ni, Cu, Zn and Pd) in the stable binaries, the stabilization effect of these elements on the metastable binaries and the formation of ternary compounds are specified and compared. While the solubility of all these TMs in hexagonal μ-Al 4 Mn and λ-Al 4 Mn is low, the high-temperature orthorhombic T-Al 3 Mn dissolves up to at least 14.5, 12, 16 and 7.5 at.% Fe, Cu, Zn and Pd, respectively. The metastable hexagonal φ-Al 10 Mn 3 is stabilized by Fe, Co and Ni in wide ternary compositional regions, and in Al Co Mn such a region propagates up to Al 5 Co 2 . In alloys with Fe, Co and Ni, a ternary hexagonal phase isostructural to the Al Cr Ni ζ-phase ( P 6 3 / m , a  ≈ 1.76, c  ≈ 1.25 nm) is formed along ∼80 at.% Al, while in alloys with Cu and Pd the orthorhombic so-called R-phase ( Bbmm , a  ≈ 2.41, b  ≈ 1.25, c  ≈ 0.76 nm) was found at similar compositions. This structure is also known in Al Zn Mn but at much lower-Al Al 68 Zn 14.5 Mn 17.5 , while in the range of 75–80 at.% Al a monoclinic phase isostructural to η-Al 11 Cr 2 ( C 2/ c , a ≈ 1.76, b  ≈ 3.04, c  ≈ 1.76 nm, β  ≈ 90°) is formed. In addition to the stable decagonal D 3 -phase in Al Fe Mn and Al Pd Mn reported earlier, the stabilization of binary Al Mn D 3 -phase was revealed around Al 64 Cu 20 Mn 16 ." @default.
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• W2316188056 date "2016-08-01" @default.
• W2316188056 modified "2023-09-23" @default.
• W2316188056 title "Ternary phases forming adjacent to Al 3 Mn Al 4 Mn in Al Mn TM (TM = Fe, Co, Ni, Cu, Zn, Pd)" @default.
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• W2316188056 doi "https://doi.org/10.1016/j.jallcom.2016.03.220" @default.
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