FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316188845> ?p ?o ?g. }

• W2316188845 endingPage "14269" @default.
• W2316188845 startingPage "14264" @default.
• W2316188845 abstract "Ln-dpp-DO3A-based complexes [dpp is a pendant diphenylphosphinamide moiety and DO3A is 1,4,7-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecane] exhibit pH-responsive reversible ligation of the phosphinamide for both the gadolinium(III) and europium(III) analogues. pKa values were 8.1 (±0.1) and 7.8 (±0.1) for Gd.1 and Gd.2, respectively. The relaxivities (20 MHz, 298 K) of the gadolinium(III) analogues were r1 = 7.9 mM(-1) s(-1) (Gd.1) and r1 = 8.2 mM(-1) s(-1) (Gd.2) in acidic media, corresponding to a hydration state q = 2; in basic media, deprotonation and coordination of the phosphinamide occurs, with r1 = 5.4 mM(-1) s(-1) (Gd.1) and r1 = 4.4 mM(-1) s(-1) (Gd.2) corresponding to q = 1. Sensitized luminescent emission was observed from the europium(III) analogues following excitation at λex = 270 nm. The hydration state values of the europium(III) analogues were consistent with those of the gadolinium(III) complexes, i.e., q = 1 and 2 in basic and acidic media, respectively. The ratio of the emission intensities of the ΔJ = 1 and 2 bands enables concentration-independent reporting of the pH. Excited-state pKa values were 8.3 (±0.1) and 8.5 (±0.1) for Eu.1 and Eu.2, respectively." @default.
• W2316188845 created "2016-06-24" @default.
• W2316188845 creator A5010109904 @default.
• W2316188845 creator A5030743273 @default.
• W2316188845 creator A5072130830 @default.
• W2316188845 date "2013-12-04" @default.
• W2316188845 modified "2023-10-16" @default.
• W2316188845 title "pH-Responsive Lanthanide Complexes Based on Reversible Ligation of a Diphenylphosphinamide" @default.
• W2316188845 cites W138860627 @default.
• W2316188845 cites W1492726842 @default.
• W2316188845 cites W1676322954 @default.
• W2316188845 cites W1964454081 @default.
• W2316188845 cites W1969137131 @default.
• W2316188845 cites W1974091186 @default.
• W2316188845 cites W1977769678 @default.
• W2316188845 cites W1981532832 @default.
• W2316188845 cites W1983768140 @default.
• W2316188845 cites W1984163069 @default.
• W2316188845 cites W1984577230 @default.
• W2316188845 cites W1988754328 @default.
• W2316188845 cites W1988985434 @default.
• W2316188845 cites W1990323385 @default.
• W2316188845 cites W1991347745 @default.
• W2316188845 cites W1997362067 @default.
• W2316188845 cites W1999889302 @default.
• W2316188845 cites W2004430934 @default.
• W2316188845 cites W2006909084 @default.
• W2316188845 cites W2007066308 @default.
• W2316188845 cites W2009834827 @default.
• W2316188845 cites W2011185698 @default.
• W2316188845 cites W2028090532 @default.
• W2316188845 cites W2033503179 @default.
• W2316188845 cites W2041612047 @default.
• W2316188845 cites W2044913289 @default.
• W2316188845 cites W2049231997 @default.
• W2316188845 cites W2049679159 @default.
• W2316188845 cites W2054297766 @default.
• W2316188845 cites W2057185918 @default.
• W2316188845 cites W2059135111 @default.
• W2316188845 cites W2060852485 @default.
• W2316188845 cites W2091130738 @default.
• W2316188845 cites W2096293149 @default.
• W2316188845 cites W2099021383 @default.
• W2316188845 cites W2100194443 @default.
• W2316188845 cites W2100516446 @default.
• W2316188845 cites W2103056992 @default.
• W2316188845 cites W2111361116 @default.
• W2316188845 cites W2111893502 @default.
• W2316188845 cites W2117911889 @default.
• W2316188845 cites W2119220514 @default.
• W2316188845 cites W2134956630 @default.
• W2316188845 cites W2152775093 @default.
• W2316188845 cites W2233674874 @default.
• W2316188845 cites W2504172113 @default.
• W2316188845 cites W2950428398 @default.
• W2316188845 cites W4232969681 @default.
• W2316188845 doi "https://doi.org/10.1021/ic402205j" @default.
• W2316188845 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24304151" @default.
• W2316188845 hasPublicationYear "2013" @default.
• W2316188845 type Work @default.
• W2316188845 sameAs 2316188845 @default.
• W2316188845 citedByCount "4" @default.
• W2316188845 countsByYear W23161888452017 @default.
• W2316188845 countsByYear W23161888452018 @default.
• W2316188845 crossrefType "journal-article" @default.
• W2316188845 hasAuthorship W2316188845A5010109904 @default.
• W2316188845 hasAuthorship W2316188845A5030743273 @default.
• W2316188845 hasAuthorship W2316188845A5072130830 @default.
• W2316188845 hasConcept C118629725 @default.
• W2316188845 hasConcept C121332964 @default.
• W2316188845 hasConcept C145148216 @default.
• W2316188845 hasConcept C148869448 @default.
• W2316188845 hasConcept C178790620 @default.
• W2316188845 hasConcept C179104552 @default.
• W2316188845 hasConcept C181500209 @default.
• W2316188845 hasConcept C185544564 @default.
• W2316188845 hasConcept C185592680 @default.
• W2316188845 hasConcept C201770740 @default.
• W2316188845 hasConcept C2776568683 @default.
• W2316188845 hasConcept C49040817 @default.
• W2316188845 hasConcept C502696234 @default.
• W2316188845 hasConcept C557651011 @default.
• W2316188845 hasConcept C71240020 @default.
• W2316188845 hasConcept C8010536 @default.
• W2316188845 hasConceptScore W2316188845C118629725 @default.
• W2316188845 hasConceptScore W2316188845C121332964 @default.
• W2316188845 hasConceptScore W2316188845C145148216 @default.
• W2316188845 hasConceptScore W2316188845C148869448 @default.
• W2316188845 hasConceptScore W2316188845C178790620 @default.
• W2316188845 hasConceptScore W2316188845C179104552 @default.
• W2316188845 hasConceptScore W2316188845C181500209 @default.
• W2316188845 hasConceptScore W2316188845C185544564 @default.
• W2316188845 hasConceptScore W2316188845C185592680 @default.
• W2316188845 hasConceptScore W2316188845C201770740 @default.
• W2316188845 hasConceptScore W2316188845C2776568683 @default.
• W2316188845 hasConceptScore W2316188845C49040817 @default.
• W2316188845 hasConceptScore W2316188845C502696234 @default.
• W2316188845 hasConceptScore W2316188845C557651011 @default.

• next