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• W2316249983 abstract "On the basis of the 120 x 120 complete energy matrix, the local lattice structures of the octahedral (CrO6)9- clusters for Cr3+ ions doping in a variety of oxide crystals with D3d or C3v site symmetry have been studied by employing two distorted parameters, respectively. By simulating the calculated EPR and optical spectra data to the experimental results, the local lattice structure parameters are determined unambiguously. It is shown, by means of a series of calculations, that although the local lattice structures around the M (M = Al3+, Ga3+, Li+, Sc3+, etc.) ions in host crystals are obviously different, the local lattice structures of the octahedral (CrO6)9- clusters in a variety of oxide crystals doped with Cr3+ ions are similar and fluctuant in the vicinity of that of the Cr2O3. This may be ascribed to the fact that there is the similarly octahedral (CrO6)9- clusters in a variety of oxide crystals doped with Cr3+ and the Cr2O3 crystal. Our viewpoint is consistent with that of Gaudry et al. [Phys. Rev. B 2003, 67, 094108]." @default.
• W2316249983 created "2016-06-24" @default.
• W2316249983 creator A5038976335 @default.
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• W2316249983 date "2008-01-01" @default.
• W2316249983 modified "2023-09-24" @default.
• W2316249983 title "Local Lattice Structure Study of the Octahedral (CrO₆)^9- Clusters for Cr³⁺ Ion Doping in a Variety of Oxide Crystals by Simulating the Corresponding EPR and Optical Spectra" @default.
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• W2316249983 doi "https://doi.org/10.1021/jp076256+" @default.
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