FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316285951> ?p ?o ?g. }

• W2316285951 endingPage "1710" @default.
• W2316285951 startingPage "1703" @default.
• W2316285951 abstract "Supported Pd nanowire and cuboctahedron catalysts have been synthesized in an ethylene glycol–poly(vinylpyrrolidone)–KBr system using a precipitation–reduction method. KBr plays a critical role in controlling the morphology of Pd: with a variety of relatively low KBr concentrations, Pd nanowires with different lengths were obtained, but after adding sufficient KBr, shape evolution from nanowires to cuboctahedrons was observed. HRTEM images showed that the twisted Pd nanowires were actually composed of primary cuboctahedrons. Furthermore, lattice distortion was observed at interfacial regions, and the number of crystal boundaries increased with increasing length of the nanowires. The catalytic performance of the Pd materials was investigated in the selective hydrogenation of acetylene. The activities of the Pd nanowire catalysts were significantly higher than those of the cuboctahedron catalyst and gradually increased with the increasing number of crystal boundaries, indicating that the defect sites at crystal boundaries are more active owing to the exposure of larger numbers of Pd atoms. However, higher activity resulted in excessive hydrogenation and a decrease in ethylene selectivity. Therefore, the Pd cuboctahedron catalyst possessed higher selectivity. The relationship between crystal boundaries and catalytic performance was quantified, and the catalytic activity was found to increase linearly with an increasing number of crystal boundaries, whereas the trend in the selectivity was the reverse." @default.
• W2316285951 created "2016-06-24" @default.
• W2316285951 creator A5011895543 @default.
• W2316285951 creator A5031411023 @default.
• W2316285951 creator A5032950983 @default.
• W2316285951 creator A5052932306 @default.
• W2316285951 date "2012-07-17" @default.
• W2316285951 modified "2023-10-02" @default.
• W2316285951 title "Controllable Synthesis and Acetylene Hydrogenation Performance of Supported Pd Nanowire and Cuboctahedron Catalysts" @default.
• W2316285951 cites W1594756461 @default.
• W2316285951 cites W1963518811 @default.
• W2316285951 cites W1963583394 @default.
• W2316285951 cites W1966935894 @default.
• W2316285951 cites W1968261633 @default.
• W2316285951 cites W1975739353 @default.
• W2316285951 cites W1977556262 @default.
• W2316285951 cites W1979631849 @default.
• W2316285951 cites W1980378453 @default.
• W2316285951 cites W1983659117 @default.
• W2316285951 cites W1984200272 @default.
• W2316285951 cites W1987856393 @default.
• W2316285951 cites W1987968007 @default.
• W2316285951 cites W1993332534 @default.
• W2316285951 cites W1993634646 @default.
• W2316285951 cites W1994029925 @default.
• W2316285951 cites W1995271098 @default.
• W2316285951 cites W1996202013 @default.
• W2316285951 cites W1996392122 @default.
• W2316285951 cites W2002222231 @default.
• W2316285951 cites W2007963901 @default.
• W2316285951 cites W2008817603 @default.
• W2316285951 cites W2012785401 @default.
• W2316285951 cites W2015847862 @default.
• W2316285951 cites W2015898189 @default.
• W2316285951 cites W2025450830 @default.
• W2316285951 cites W2025605690 @default.
• W2316285951 cites W2031445539 @default.
• W2316285951 cites W2033087873 @default.
• W2316285951 cites W2033921985 @default.
• W2316285951 cites W2034749870 @default.
• W2316285951 cites W2035320135 @default.
• W2316285951 cites W2035353290 @default.
• W2316285951 cites W2037858560 @default.
• W2316285951 cites W2038271246 @default.
• W2316285951 cites W2038276266 @default.
• W2316285951 cites W2041260375 @default.
• W2316285951 cites W2042175392 @default.
• W2316285951 cites W2047066023 @default.
• W2316285951 cites W2047522544 @default.
• W2316285951 cites W2049273027 @default.
• W2316285951 cites W2056518908 @default.
• W2316285951 cites W2056550044 @default.
• W2316285951 cites W2057041620 @default.
• W2316285951 cites W2060952962 @default.
• W2316285951 cites W2062476650 @default.
• W2316285951 cites W2068003132 @default.
• W2316285951 cites W2071346857 @default.
• W2316285951 cites W2078013940 @default.
• W2316285951 cites W2080374105 @default.
• W2316285951 cites W2092274698 @default.
• W2316285951 cites W2126799157 @default.
• W2316285951 cites W2166209808 @default.
• W2316285951 cites W2314675732 @default.
• W2316285951 cites W2315108600 @default.
• W2316285951 cites W2333481898 @default.
• W2316285951 cites W2949147218 @default.
• W2316285951 cites W2952197153 @default.
• W2316285951 cites W4206224314 @default.
• W2316285951 cites W4236262164 @default.
• W2316285951 cites W4361854982 @default.
• W2316285951 doi "https://doi.org/10.1021/cs300224j" @default.
• W2316285951 hasPublicationYear "2012" @default.
• W2316285951 type Work @default.
• W2316285951 sameAs 2316285951 @default.
• W2316285951 citedByCount "61" @default.
• W2316285951 countsByYear W23162859512014 @default.
• W2316285951 countsByYear W23162859512015 @default.
• W2316285951 countsByYear W23162859512016 @default.
• W2316285951 countsByYear W23162859512017 @default.
• W2316285951 countsByYear W23162859512018 @default.
• W2316285951 countsByYear W23162859512019 @default.
• W2316285951 countsByYear W23162859512020 @default.
• W2316285951 countsByYear W23162859512021 @default.
• W2316285951 countsByYear W23162859512022 @default.
• W2316285951 countsByYear W23162859512023 @default.
• W2316285951 crossrefType "journal-article" @default.
• W2316285951 hasAuthorship W2316285951A5011895543 @default.
• W2316285951 hasAuthorship W2316285951A5031411023 @default.
• W2316285951 hasAuthorship W2316285951A5032950983 @default.
• W2316285951 hasAuthorship W2316285951A5052932306 @default.
• W2316285951 hasConcept C115624301 @default.
• W2316285951 hasConcept C118792377 @default.
• W2316285951 hasConcept C127413603 @default.
• W2316285951 hasConcept C146088050 @default.
• W2316285951 hasConcept C161368742 @default.
• W2316285951 hasConcept C161790260 @default.
• W2316285951 hasConcept C171250308 @default.
• W2316285951 hasConcept C178790620 @default.

• next