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• W2316304098 endingPage "3184" @default.
• W2316304098 startingPage "3174" @default.
• W2316304098 abstract "The synthesis and characterization of 1,5-bis(2,6-diisopropylphenyl)-2,4-diphenyl-1,3,5-triazapenta-1,3-diene (L1H), a triaza ligand, and Al complexes of its anion are reported. A neat condensation reaction between N-(Dipp)benzamidine (Dipp = 2,6-diisopropylphenyl) and N-(Dipp)benzimidoyl chloride affords L1H in good yield. The Al complexes [L1AlMe2] (1), [L1AlMe(Cl)] (2), and [L1AlCl2] (3) are prepared by treating L1H with a slight excess of AlMe3, AlMe2Cl, and AlMeCl2, respectively, in toluene. Further, the aluminum complexes [L2AlMe2] (5), [L2AlMe(Cl)] (6), and [L2AlCl2] (7) are obtained in good yields from 1,3-bis(2-pyridylimino)isoindoline (L2H) in a similar fashion. The ligand L1H and complexes 1, 2, and 4–6 have been structurally characterized. All of the complexes have been explored for their catalytic activity toward the ring-opening polymerization (ROP) of ε-caprolactone. It has been found that [L1AlMe2], upon the addition of cocatalyst (benzyl alcohol), gives a tetranuclear Al alkoxide (8), which is highly efficient in catalyzing the ROP of ε-caprolactone. [L2AlMe2] has also been found to be a good catalyst. The crystal structure of 8 and the catalytic activities of all the complexes in detail are reported." @default.
• W2316304098 created "2016-06-24" @default.
• W2316304098 creator A5036801121 @default.
• W2316304098 creator A5085637097 @default.
• W2316304098 date "2013-05-24" @default.
• W2316304098 modified "2023-10-14" @default.
• W2316304098 title "Synthesis of Aluminum Complexes of Triaza Framework Ligands and Their Catalytic Activity toward Polymerization of ε-Caprolactone" @default.
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• W2316304098 doi "https://doi.org/10.1021/om3011432" @default.
• W2316304098 hasPublicationYear "2013" @default.
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