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• W2316365616 abstract "With the aid of molecular dynamics simulation, we consider why the diffusivity of liquid becomes slower as the liquid is confined to a narrower space. The diffusion coefficient of octamethylcyclotetrasiloxane liquid confined between two mica surfaces was calculated for a range of surface separations from 64 to 23 Å. The resulting separation dependence of the diffusion coefficient can be explained by considering that the molecular diffusion is an activated process. In particular, we find that the increase in the activation energy is closely correlated with the decrease of the potential energy per molecule, from which we propose a molecular-level mechanism of this confined-induced diffusion slowdown." @default.
• W2316365616 created "2016-06-24" @default.
• W2316365616 creator A5004679348 @default.
• W2316365616 creator A5070143245 @default.
• W2316365616 creator A5081661489 @default.
• W2316365616 date "2012-11-07" @default.
• W2316365616 modified "2023-09-23" @default.
• W2316365616 title "Mechanism of Diffusion Slowdown in Confined Liquids" @default.
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• W2316365616 doi "https://doi.org/10.1103/physrevlett.109.197801" @default.
• W2316365616 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23215427" @default.
• W2316365616 hasPublicationYear "2012" @default.
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