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- W2316386048 abstract "Recent reports on the organic structure-directing agent (OSDA)-free synthesis of some zeolites with the aid of seed crystals have opened a new way to the robust and environmentally friendly production of industrially valuable zeolites. However, the details on the crystallization behavior as well as the role of the seeds have not been fully clarified yet. In this study, the crystallization process of zeolite beta in the OSDA-free, seed-embedded Na+−aluminosilicate gel system, which never yields beta in the absence of the seeds, is investigated in detail. The XRD and TEM studies of the solid aluminosilicate products in the course of the hydrothermal treatment suggest that the crystallization of zeolite beta proceeds on the outer surface of amorphous aluminosilicates. The Raman spectroscopy, solid-state 27Al and 23Na MAS NMR and high-energy XRD analyses of seeded and nonseeded amorphous materials just before crystallization reveal that the beta seeds induce no major changes in their structures, implying that..." @default.
- W2316386048 created "2016-06-24" @default.
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- W2316386048 date "2010-12-27" @default.
- W2316386048 modified "2023-10-14" @default.
- W2316386048 title "Crystallization Behavior of Zeolite Beta in OSDA-Free, Seed-Assisted Synthesis" @default.
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- W2316386048 doi "https://doi.org/10.1021/jp1098975" @default.
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