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- W2316391204 abstract "Liquid-vapour equilibrium data are given for the systems acetone+nitromethane and acetone+acetonitrile at 45.00 �C. The data are used to calculate the excess free energy of mixing for these systems. The former system has a negative value of the excess free energy of mixing and shows a change in sign of the deviation of the activity of nitromethane from the Raoults law value at a mole fraction of acetone of 0.36. A value of the virial coefficient β12 in the equation of state of the mixed vapours was estimated from the equilibrium data for this system. The excess free energy of mixing for the system acetone+acetonitrile is zero within the experimental error over the whole concentration range. The Stockmayer potential was used to calculate values of β12, for the binary systems formed from acetone, nitromethane, and acetonitrile. For the system acetone+nitromethane the value estimated from our data is more negative than the value calculated using the Stockmayer potential, indicating a specific interaction, possibly hydrogen bonding, between the acetone and nitromethane molecules." @default.
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- W2316391204 date "1960-01-01" @default.
- W2316391204 modified "2023-09-30" @default.
- W2316391204 title "Liquid-Vapour Equilibria. X. The Systems Acetone+Nitromethane and Acetone+Acetonitrile at 45°C" @default.
- W2316391204 doi "https://doi.org/10.1071/ch9600030" @default.
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