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- W2316392001 abstract "ポリオキシエチレン (POE) 鎖長 (n) の異なる4種類の非イオン界面活性剤 {ヘキサデシルポリオキシエチレンエーテル (C16POEn;n-10, 20, 30, 40)} を用いた合成香料 {2-フェニルエチルアルコール (PEA), ベンジルアセテート (BA), d-リモネン (LN)} の可溶化を, 可溶化平衡定数およびミセル粒子径の測定から検討した。香料の可溶化平衡定数は, 非イオン界面活性剤のPOE鎖長あるいは香料のHLB値の増加に伴い減少した。ミセル中におけるPEAの活量係数は他の香料よりかなり小さく, 0.1～0.2であった。また, 香料1分子を可溶化するのに必要な界面活性剤の分子数 (2B値) は, LNの場合0.7～1.0, BAの場合0.4～1.0, PEAの場合1.7～2.8であった。さらに, C16POE10ミセルの粒子径はPEAの可溶化量の増加に伴い増大した。これらのことから, PEAはLNやBAに比べ, より強くミセル親水部のPOE鎖 (親水基) に吸着し, POE鎖の脱水和を誘起することが示唆された。" @default.
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- W2316392001 date "1995-01-01" @default.
- W2316392001 modified "2023-10-18" @default.
- W2316392001 title "Solubilization Equilibrium Constants of Synthetic Perfumes in the Micellar Solutions of Nonionic Surfactants" @default.
- W2316392001 doi "https://doi.org/10.4011/shikizai1937.68.271" @default.
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