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- W2316396928 abstract "In the asymmetric unit of the title compound, (C16H38N2O6)[Zn(C3S5)2], two independent cations lie across inversion centers. In one of the cations, the three symmetry-unique O-H groups are disordered over two sets of sites with refined occupancy ratios of 0.701 (9):0.299 (9), 0.671 (8):0.329 (8) and 0.566 (7):0.434 (7). In the anion, the Zn(II) ion is coordinated in a distorted tetra-hedral environment by four S atoms of two chelating 1,3-di-thiole-2-thione-4,5-dithiolato ligands. The dihedral angle between the mean planes [maximun deviations = 0.022 (3) and 0.0656 (6) Å] of the two ligands is 87.76 (3)°. An intamolecular O-H⋯O hydrogen bond occurs in the disordered cation. In the crystal, O-H⋯O and O-H⋯S hydrogen bonds link the components into a two-dimensional network parallel to (0-11)." @default.
- W2316396928 created "2016-06-24" @default.
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- W2316396928 date "2013-06-08" @default.
- W2316396928 modified "2023-09-25" @default.
- W2316396928 title "<i>N</i>,<i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′,<i>N</i>′-Hexakis(2-hydroxyethyl)butane-1,4-diaminium bis(2-sulfanylidene-1,3-dithiole-4,5-dithiolato-κ<sup>2</sup><i>S</i><sup>4</sup>,<i>S</i><sup>5</sup>)zincate" @default.
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- W2316396928 doi "https://doi.org/10.1107/s1600536813014992" @default.
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