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- W2316400818 abstract "Frequency-dependent electrical conductivities of solutions of aqueous sodium chloride have been measured from T = 298 K to T = 623 K at p = 20 MPa, over a very wide range of ionic strength (2·10–5 to 0.17 mol·kg–1) using a unique high-precision flow-through alternating current (AC) electrical conductance instrument. Experimental values for the equivalent conductivity, Λ, were used to calculate molar conductivities at infinite dilution, Λ°, using the Fuoss–Hsia–Fernandez–Prini (FHFP) and Turq–Blum–Bernard–Kunz (TBBK) ionic conductivity models. The resulting values for the limiting conductivity Λ° and the ion association constant of NaCl, from this work and critically evaluated literature data above 277 K, were represented to within the combined experimental uncertainties, as functions of viscosity and solvent density, respectively. New values and new correlations are reported for the limiting equivalent conductivities of the sodium ion, λ°(Na+), and the chloride ion, λ°(Cl–) from 277 K and 100 kPa to 1073 ..." @default.
- W2316400818 created "2016-06-24" @default.
- W2316400818 creator A5002846566 @default.
- W2316400818 creator A5079515619 @default.
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- W2316400818 date "2012-08-29" @default.
- W2316400818 modified "2023-09-26" @default.
- W2316400818 title "Limiting Conductivities and Ion Association Constants of Aqueous NaCl under Hydrothermal Conditions: Experimental Data and Correlations" @default.
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- W2316400818 doi "https://doi.org/10.1021/je300361j" @default.
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