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- W2316492716 startingPage "7153" @default.
- W2316492716 abstract "The Lewis acidic character of alkyl- and arylplatinum complexes has been investigated within density functional theory with an emphasis on supramolecular structures (e.g., buckybowls, fullerenes, and nanotubes) doped with Pt atoms. By selective substitution of a single atom within a larger carbon framework with a Pt atom, the resulting species demonstrate a strong preference for interaction with small organic molecules, particularly polar substances via a Lewis acid/Lewis base complexation. Coordination with CO and maleic anhydride offers a gauge of comparing the Lewis acidity of these alkyl- and arylplatinum complexes. We have also examined the use of these organometallic species as catalysts for the Diels−Alder reaction and have found that curved π-conjugation and delocalization of electrons offer modest rate enhancements and improvements in selectivity. Preliminary results suggest that extended molecular architectures such as Pt-doped nanotubes may provide selectivities that differ from that of traditional Lewis acid catalysts." @default.
- W2316492716 created "2016-06-24" @default.
- W2316492716 creator A5042951744 @default.
- W2316492716 creator A5056710816 @default.
- W2316492716 date "2011-03-29" @default.
- W2316492716 modified "2023-09-27" @default.
- W2316492716 title "Lewis Acidity of Pt-Doped Buckybowls, Fullerenes, and Single-Walled Carbon Nanotubes" @default.
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- W2316492716 doi "https://doi.org/10.1021/jp108174b" @default.
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