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• W2316495420 endingPage "4550" @default.
• W2316495420 startingPage "4544" @default.
• W2316495420 abstract "The complex [Pd(azoMe)(κ1-dppm)(κ2-dppm)]TfO (azoMe = 2-(4‘-tolylazo)-5-methylphenyl, dppm = bis(diphenylphosphino)methane, TfO = CF3SO3) reacts at room temperature with aryl azides N3Ar to give, in moderate to high yields, iminophosphorane complexes [Pd(κ2-azoMe-C,N‘){κ2-PPh2CH2P(NAr)Ph2-P,N}]TfO [Ar = C6H4R, R = H (1), MeO-2 (2a), Me-2 (2b), NO2-2 (2c), MeO-3 (3a), NO2-3 (3c), MeO-4 (4a), Me-4 (4b), NO2-4 (4c)]. In all cases, there is a linear correlation between δ(P) (ppm) of both phosphorus atoms and temperature T (°C) [δ(P1) = δ1(0) + a1T; δ(P2) = δ2(0) + a2T]. In the ortho-substituted complexes 2a−c and the nitro derivatives 3c and 4c, crossing of the two δ/T plots of each complex is not observed and the change in chemical shift with temperature is small or nil, |a1|, |a2| = (0−12) × 10-3 ppm/°C. In the other complexes, the gradient of one of the straight lines is positive (a1 ≈ 26 × 10-3 ppm/°C) and that of the other is negative (a2 ≈ −7.5 × 10-3 ppm/°C). Both lines cross in the range 0−25 °C. 4b reacts with [Au(acac)PPh3] (1:2) to give [Pd(azoMe-C,N‘){PPh2C(AuPPh3)2P(NAr)Ph2-P,N}] [Ar = Me-4 (5b)]. [Pd(azoMe-C,N‘)(κ2-dppm)]TfO reacts with NaN3 to give [Pd2(azoMe)2(μ2-N3)(μ2-dppm)2]TfO (6). The crystal structure of 4b is reported." @default.
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• W2316495420 date "1998-09-12" @default.
• W2316495420 modified "2023-10-03" @default.
• W2316495420 title "Palladium(II) Complexes of Monoaryliminophosphorane Derivatives of 1,2-Bis(Diphenylphosphino)methane. Crystal Structure of [Pd{κ²-C₆H₃(NN−C₆H₄Me-4‘)-2- (C₆H₄Me-4‘‘)-5-<i>C</i>,<i>N</i>‘}{κ²-PPh₂CH₂P(NC₆H₄Me-4)Ph₂-<i>P</i>,<i>N</i>}]" @default.
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• W2316495420 cites W1966014099 @default.
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• W2316495420 cites W1973089554 @default.
• W2316495420 cites W1975459520 @default.
• W2316495420 cites W1977764517 @default.
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• W2316495420 cites W1992522924 @default.
• W2316495420 cites W1993920823 @default.
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• W2316495420 cites W2006967774 @default.
• W2316495420 cites W2008000308 @default.
• W2316495420 cites W2008070626 @default.
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• W2316495420 cites W2015323117 @default.
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• W2316495420 cites W2023768115 @default.
• W2316495420 cites W2027962489 @default.
• W2316495420 cites W2028850022 @default.
• W2316495420 cites W2030106398 @default.
• W2316495420 cites W2033594709 @default.
• W2316495420 cites W2035181276 @default.
• W2316495420 cites W2035603999 @default.
• W2316495420 cites W2040183266 @default.
• W2316495420 cites W2040631183 @default.
• W2316495420 cites W2041412413 @default.
• W2316495420 cites W2043816089 @default.
• W2316495420 cites W2044593252 @default.
• W2316495420 cites W2047625221 @default.
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• W2316495420 cites W2052873023 @default.
• W2316495420 cites W2053286423 @default.
• W2316495420 cites W2068983249 @default.
• W2316495420 cites W2081267864 @default.
• W2316495420 cites W2090116528 @default.
• W2316495420 cites W2094237196 @default.
• W2316495420 cites W2094751359 @default.
• W2316495420 cites W2095308408 @default.
• W2316495420 cites W2102483061 @default.
• W2316495420 cites W2106515067 @default.
• W2316495420 cites W2129645440 @default.
• W2316495420 cites W2138661568 @default.
• W2316495420 cites W2142170272 @default.
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• W2316495420 cites W2464142152 @default.
• W2316495420 cites W2472980444 @default.
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• W2316495420 doi "https://doi.org/10.1021/om980445k" @default.
• W2316495420 hasPublicationYear "1998" @default.
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