FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316522392> ?p ?o ?g. }

• W2316522392 endingPage "76" @default.
• W2316522392 startingPage "66" @default.
• W2316522392 abstract "Background: Nanocomposites consisting of spatially confined polymeric chains are of great interest due to their application in optoelectronic and photonics devices. Polymer layered silicate nanocomposites have attracted much attention in industry as well as academia owing to their remarkable physical and chemical properties as compared to conventional polymer nanocomposites. Methods: In present study, comparative investigation of the in-situ polymerization of poly(ophenylenediamine) intercalated montmorillonite has been done via two methods i.e using poly(o-phenylenediamine) as filler for MMT in one case and as matrix in the other. Intercalation and in-situ polymerization was confirmed by FT-IR, UV-Visible spectroscopy and XRD studies. TEM and optical microscopy studies confirmed the self-assembled morphology of nanocomposites while the fluorescence properties revealed that controlled emission could be achieved by confining poly(o-phenylenediamine) in MMT galleries. Result: Intercalation and in-situ polymerization of o-phenylenediamine within MMT was successfully carried out using sonochemical technique. The growth of conducting polymers in the interlayer region of the clays has been shown to dramatically improve the properties of conducting polymers. Also, the loading of the polymer in the MMT has shown to influence the optical properties of the nanocomposite. IR spectra and XRD analysis confirmed the intercalation of POPD and its polymerization within the clay galleries. UV spectra revealed the doped state of POPD within clay galleries. Highest oscillator strength of 0.0137 was observed for POPD:MMT-1:0.25. Spherical self-assembled morphology was attained for POPD:MMT-1:0.25. XRD revealed major shift of 82.5 Å for the nanocomposite POPD:MMT-1:1, POPD:MMT-1:0.5 and MMT:POPD-1:0.25. Blue shift of 20 nm was noticed in the fluorescence spectra of POPD:MMT-1:0.25 and POPD:MMT-1:0.5 which was correlated to the intense interaction between NH of POPD with SiO of MMT. Highest quantum yield of 0.345 was achieved in case of POPD:MMT-1:0.25. The gallery confinement was found to control the optical as well as morphological characteristics of the nanocomposite. The controlled growth of POPD chains and their minimum aggregation resulted in the formation of self-assembled morphology. Thus, by choosing the optimum filler loading and by controlling its interaction with the matrix, nanocomposites with controlled architecture can be designed. Conclusion: It can be concluded that intercalation and exfoliation of nanocomposites largely depends on the experimental conditions such as type of conducting monomer, clay and organic modifier etc. The preparation technique and processing conditions influence the overall properties of the nanocomposites. Thus, by choosing the optimum filler loading and by controlling its interaction with the matrix, nanocomposites with controlled architecture can be designed. Few relevant patents to the topic have been reviewed and cited. Keywords: Conducting polymer, fluorescence, Intercalation, MMT, morphology." @default.
• W2316522392 created "2016-06-24" @default.
• W2316522392 creator A5020142065 @default.
• W2316522392 creator A5082384485 @default.
• W2316522392 creator A5084023238 @default.
• W2316522392 date "2016-03-22" @default.
• W2316522392 modified "2023-10-18" @default.
• W2316522392 title "Influence of Conducting Polymer as Filler and Matrix on the Spectral, Morphological and Fluorescent Properties of Sonochemically Intercalated poly(o-phenylenediamine)/Montmorillonite Nanocomposites" @default.
• W2316522392 doi "https://doi.org/10.2174/1872210510999160316122403" @default.
• W2316522392 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27018274" @default.
• W2316522392 hasPublicationYear "2016" @default.
• W2316522392 type Work @default.
• W2316522392 sameAs 2316522392 @default.
• W2316522392 citedByCount "8" @default.
• W2316522392 countsByYear W23165223922017 @default.
• W2316522392 countsByYear W23165223922018 @default.
• W2316522392 countsByYear W23165223922021 @default.
• W2316522392 countsByYear W23165223922022 @default.
• W2316522392 countsByYear W23165223922023 @default.
• W2316522392 crossrefType "journal-article" @default.
• W2316522392 hasAuthorship W2316522392A5020142065 @default.
• W2316522392 hasAuthorship W2316522392A5082384485 @default.
• W2316522392 hasAuthorship W2316522392A5084023238 @default.
• W2316522392 hasConcept C127413603 @default.
• W2316522392 hasConcept C137824038 @default.
• W2316522392 hasConcept C159985019 @default.
• W2316522392 hasConcept C178790620 @default.
• W2316522392 hasConcept C185592680 @default.
• W2316522392 hasConcept C188027245 @default.
• W2316522392 hasConcept C192562407 @default.
• W2316522392 hasConcept C2777515222 @default.
• W2316522392 hasConcept C2777835026 @default.
• W2316522392 hasConcept C2781241367 @default.
• W2316522392 hasConcept C3231350 @default.
• W2316522392 hasConcept C42360764 @default.
• W2316522392 hasConcept C44228677 @default.
• W2316522392 hasConcept C521977710 @default.
• W2316522392 hasConcept C92880739 @default.
• W2316522392 hasConceptScore W2316522392C127413603 @default.
• W2316522392 hasConceptScore W2316522392C137824038 @default.
• W2316522392 hasConceptScore W2316522392C159985019 @default.
• W2316522392 hasConceptScore W2316522392C178790620 @default.
• W2316522392 hasConceptScore W2316522392C185592680 @default.
• W2316522392 hasConceptScore W2316522392C188027245 @default.
• W2316522392 hasConceptScore W2316522392C192562407 @default.
• W2316522392 hasConceptScore W2316522392C2777515222 @default.
• W2316522392 hasConceptScore W2316522392C2777835026 @default.
• W2316522392 hasConceptScore W2316522392C2781241367 @default.
• W2316522392 hasConceptScore W2316522392C3231350 @default.
• W2316522392 hasConceptScore W2316522392C42360764 @default.
• W2316522392 hasConceptScore W2316522392C44228677 @default.
• W2316522392 hasConceptScore W2316522392C521977710 @default.
• W2316522392 hasConceptScore W2316522392C92880739 @default.
• W2316522392 hasIssue "1" @default.
• W2316522392 hasLocation W23165223921 @default.
• W2316522392 hasLocation W23165223922 @default.
• W2316522392 hasOpenAccess W2316522392 @default.
• W2316522392 hasPrimaryLocation W23165223921 @default.
• W2316522392 hasRelatedWork W1979168665 @default.
• W2316522392 hasRelatedWork W2077383263 @default.
• W2316522392 hasRelatedWork W2182047199 @default.
• W2316522392 hasRelatedWork W2287202654 @default.
• W2316522392 hasRelatedWork W2316522392 @default.
• W2316522392 hasRelatedWork W2365969487 @default.
• W2316522392 hasRelatedWork W2380119563 @default.
• W2316522392 hasRelatedWork W2385372716 @default.
• W2316522392 hasRelatedWork W2386674057 @default.
• W2316522392 hasRelatedWork W2509417546 @default.
• W2316522392 hasVolume "10" @default.
• W2316522392 isParatext "false" @default.
• W2316522392 isRetracted "false" @default.
• W2316522392 magId "2316522392" @default.
• W2316522392 workType "article" @default.