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• W2316546906 abstract "Cu(In, Ga)<TEX>$Se_2$</TEX> (CIGS) 박막은 다원화합물이기 때문에 제조공정이 매우 까다롭다. 진공장치를 사용하는 제조 방법으로 동시증착법, 스퍼터링법 +셀렌화가 있고, 비진공 제조 방법으로 전기화학적인 전착법이 있다. 각 방법에 있어서도 출발 물질의 종류에 따라 다양한 제조 방법이 동원 될 수 있다. 진공증착에 의한 방법은 고품질의 박막을 얻는데 사용 되고 있으나 고가의 진공장비가 사용되므로 대면적화에 따른 제조비용 측면에서 문제가 있다. 이에 비하여, 전착법은 간단하면서도 저가로 대면적화를 이룰 수 있다는 장점 때문에, 많은 관심이 기울여지고 있다. 본 연구에서는 Mo/Glass전극위에 Ga/(In + Ga) = 0.3의 성분비를 만족시키는 CIGS 박막을 전기화학적으로 제조하기 위하여, <TEX>$Cu^{2+}$</TEX>, <TEX>$In^{3+}$</TEX>, <TEX>$Ga^{3+}$</TEX>, <TEX>$Se^{4+}$</TEX> 4성분을 모두 포함하는 전해질 수용액 내에서, 4성분의 이온들이 동시에 환원되는 전위를 조절하여 CIGS 박막을 전착 하였다. SEM을 이용하여 얻어진 CIGS 박막의 전착된 시료의 표면을 관찰하였고, EDS로 그 조성을 분석하였다. 또한, XRD를 이용하여 전착시료의 열처리 전후의 결정성변화를 조사하였다. The chalcopyrite <TEX>$Cu(In_xGa_{(1-x)})Se_2$</TEX> (CIGS) is considered to be one of the effective light-absorbing materials for thin film photovoltaic solar cells. We describe the electrodeposition of CIGS thin films in ambient laboratory conditions, and suggest the electrochemical conditions to prepare stoichiometric CIGS thin films of Ga/(In + Ga) = 0.3. In acidic solutions containing <TEX>$Cu^{2+}$</TEX>, <TEX>$In^{3+}$</TEX>, <TEX>$Ga^{3+}$</TEX> and <TEX>$Se^{4+}$</TEX> ions, the CIGS films of different Cu/In/Ga/Se chemical compositions were electrodeposited onto Mo/Glass substrate. The structure, morphology and chemical composition of electrodeposited CIGS films were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), and Energy dispersive X-ray spectroscopy (EDS), respectively." @default.
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• W2316546906 date "2010-05-31" @default.
• W2316546906 modified "2023-09-27" @default.
• W2316546906 title "Electrodeposition of Cu(InxGa(1-x))Se2Thin Film" @default.
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• W2316546906 doi "https://doi.org/10.5229/jkes.2010.13.2.089" @default.
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