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• W2316574902 abstract "Ten new ergosteroids, gloeophyllins A-J (1-10), have been isolated from the solid cultures of Gloeophyllum abietinum. The absolute configurations of 1, 2, and 9 were determined by X-ray crystallographic analysis. Compound 1 has a rare C-nor-D-homosteroid skeleton. Compound 9 possesses an unusual ergostane skeleton having a 10-oxabicyclo [4.3.1] decane moiety replacing 6/5 fused C/D rings. Compound 10 represents the first ergosteroid featuring the cleavage of a C8-C14 bond. The cytotoxicity of 1-10 was tested against the human cancer cell lines K562 and HCT116. The biosynthetic pathway for 1-10 is postulated." @default.
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• W2316574902 date "2015-04-27" @default.
• W2316574902 modified "2023-09-23" @default.
• W2316574902 title "Gloeophyllins A–J, Cytotoxic Ergosteroids with Various Skeletons from a Chinese Tibet Fungus <i>Gloeophyllum abietinum</i>" @default.
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• W2316574902 doi "https://doi.org/10.1021/acs.orglett.5b01080" @default.
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