FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316605407> ?p ?o ?g. }

• W2316605407 endingPage "19850" @default.
• W2316605407 startingPage "19839" @default.
• W2316605407 abstract "We report a careful characterization of the interaction of NH3 with the Cu(II) sites of the [Cu2C4O8] paddle-wheel cornerstone of the HKUST-1 metallorganic framework, also known as Cu3(BTC)2. The general picture emerging from combining XRPD, EXAFS, XANES, mid- and far-IR, DRUV–vis, and EPR techniques is that the presence of traces of water has relevant consequences on the effect of ammonia on the MOF framework. NH3 adsorption on the dry system results in a strong chemisorption on Cu(II) sites that distorts the framework, keeping the crystallinity of the material. Perturbation observed upon NH3 adsorption is analogous to that observed for H2O, but noticeably enhanced. When the adsorption of ammonia occurs in humid conditions, a time-dependent, much deeper modification of the system is observed by all of the considered techniques. On a methodological ground, it is worth noticing that we used the optimization of XANES spectra to validate the bond distance obtained by EXAFS." @default.
• W2316605407 created "2016-06-24" @default.
• W2316605407 creator A5008063541 @default.
• W2316605407 creator A5009521760 @default.
• W2316605407 creator A5016735735 @default.
• W2316605407 creator A5028889704 @default.
• W2316605407 creator A5033138022 @default.
• W2316605407 creator A5038631856 @default.
• W2316605407 creator A5065176254 @default.
• W2316605407 date "2012-09-10" @default.
• W2316605407 modified "2023-10-16" @default.
• W2316605407 title "Insights into Adsorption of NH₃ on HKUST-1 Metal–Organic Framework: A Multitechnique Approach" @default.
• W2316605407 cites W1601443306 @default.
• W2316605407 cites W1619020458 @default.
• W2316605407 cites W1655215519 @default.
• W2316605407 cites W1677701489 @default.
• W2316605407 cites W1967109824 @default.
• W2316605407 cites W1969504890 @default.
• W2316605407 cites W1969949565 @default.
• W2316605407 cites W1970023865 @default.
• W2316605407 cites W1970029334 @default.
• W2316605407 cites W1970188546 @default.
• W2316605407 cites W1972777654 @default.
• W2316605407 cites W1974959322 @default.
• W2316605407 cites W1976245248 @default.
• W2316605407 cites W1976356254 @default.
• W2316605407 cites W1976893852 @default.
• W2316605407 cites W1978723456 @default.
• W2316605407 cites W1979176389 @default.
• W2316605407 cites W1981822331 @default.
• W2316605407 cites W1982179393 @default.
• W2316605407 cites W1986022082 @default.
• W2316605407 cites W1986238480 @default.
• W2316605407 cites W1986356599 @default.
• W2316605407 cites W1990388967 @default.
• W2316605407 cites W1994694118 @default.
• W2316605407 cites W1994919884 @default.
• W2316605407 cites W1995969777 @default.
• W2316605407 cites W1996427836 @default.
• W2316605407 cites W1998449175 @default.
• W2316605407 cites W1999918445 @default.
• W2316605407 cites W1999937609 @default.
• W2316605407 cites W2000722588 @default.
• W2316605407 cites W2002710595 @default.
• W2316605407 cites W2002928929 @default.
• W2316605407 cites W2004550299 @default.
• W2316605407 cites W2005285261 @default.
• W2316605407 cites W2007333648 @default.
• W2316605407 cites W2007998078 @default.
• W2316605407 cites W2009806571 @default.
• W2316605407 cites W2015954254 @default.
• W2316605407 cites W2017828852 @default.
• W2316605407 cites W2021681830 @default.
• W2316605407 cites W2022085591 @default.
• W2316605407 cites W2022167379 @default.
• W2316605407 cites W2023692073 @default.
• W2316605407 cites W2027470655 @default.
• W2316605407 cites W2029969257 @default.
• W2316605407 cites W2032778219 @default.
• W2316605407 cites W2034571753 @default.
• W2316605407 cites W2036150407 @default.
• W2316605407 cites W2038764479 @default.
• W2316605407 cites W2039638206 @default.
• W2316605407 cites W2040995650 @default.
• W2316605407 cites W2042763612 @default.
• W2316605407 cites W2043077507 @default.
• W2316605407 cites W2045606763 @default.
• W2316605407 cites W2046080838 @default.
• W2316605407 cites W2046456297 @default.
• W2316605407 cites W2052268521 @default.
• W2316605407 cites W2054723738 @default.
• W2316605407 cites W2054817589 @default.
• W2316605407 cites W2055578004 @default.
• W2316605407 cites W2061581510 @default.
• W2316605407 cites W2062017525 @default.
• W2316605407 cites W2063012164 @default.
• W2316605407 cites W2065437484 @default.
• W2316605407 cites W2067281746 @default.
• W2316605407 cites W2070227796 @default.
• W2316605407 cites W2078444809 @default.
• W2316605407 cites W2083172037 @default.
• W2316605407 cites W2086593157 @default.
• W2316605407 cites W2090748133 @default.
• W2316605407 cites W2092541700 @default.
• W2316605407 cites W2094005838 @default.
• W2316605407 cites W2094251757 @default.
• W2316605407 cites W2099486431 @default.
• W2316605407 cites W2102312674 @default.
• W2316605407 cites W2106259156 @default.
• W2316605407 cites W2115764422 @default.
• W2316605407 cites W2116516840 @default.
• W2316605407 cites W2117150409 @default.
• W2316605407 cites W2124676824 @default.
• W2316605407 cites W2126030556 @default.
• W2316605407 cites W2145496177 @default.
• W2316605407 cites W2145532117 @default.
• W2316605407 cites W2146051607 @default.
• W2316605407 cites W2152672348 @default.

• next