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• W2316683887 abstract "Nucleophilic C−S bond formation using easily available β-hydroxysulfonate derivatives allowed direct access to new mono- and disubstituted divinyl sulfones. Our strategy uses thioethanol (HSCH2CH2OH) and its analogues such as HSCH2CH(Y)OH generated in situ. The strategy also allows the synthesis of modified divinyl sulfones attached to chiral appendages like carbohydrates. Bis-heteronucleophilic Michael addition reactions with 1 equiv of a primary amine afforded new generations of S,S-dioxothiomorpholine derivatives known for their therapeutic applications. Further synthetic manipulations of some of these cyclic compounds led to the synthesis of novel bicyclic derivatives." @default.
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• W2316683887 date "2011-03-25" @default.
• W2316683887 modified "2023-09-27" @default.
• W2316683887 title "A General Route to Mono- and Disubstituted Divinyl Sulfones: Acyclic Michael Acceptors for the Synthesis of Polyfunctionalized Cyclic Sulfones" @default.
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• W2316683887 doi "https://doi.org/10.1021/jo101877r" @default.
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