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• W2316688317 abstract "The symmetry of the hydrogen bond in hydrogen difluoromaleate monoanion is probed by X-ray crystallography and by the NMR method of isotopic perturbation in water, in two aprotic organic solvents, and in an isotropic liquid crystal. The X-ray crystal structure of potassium hydrogen difluoromaleate shows a remarkably short O–O distance of 2.41 Å and equal O–H distances of 1.206 Å, consistent with a strong and symmetric hydrogen bond. Incorporation of 18O into one carboxyl group allows investigation of the symmetry of the H-bond in solution by the method of isotopic perturbation. The 19F NMR spectra of the mono-18O-substituted monoanion in water, CD2Cl2, and CD3CN show an AB spin system, corresponding to fluorines in different environments. The difference is attributed to the perturbation of the acidity of a carboxylic acid by 18O, not to the mere presence of the 18O, because the mono-18O dianion shows equivalent fluorines. Therefore, it is concluded that the monoanion exists as an equilibrating pair of interconverting tautomers and not as a single symmetric structure not only in water but also in organic solvents. However, in the isotropic liquid crystal phase of 4-cyanophenyl 4-heptylbenzoate, tetrabutylammonium hydrogen difluoromaleate-18O shows equivalent fluorines, consistent with a single symmetric structure. These results support earlier studies, which suggested that the symmetry of hydrogen bonds can be determined by the local environment." @default.
• W2316688317 created "2016-06-24" @default.
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• W2316688317 date "2012-05-01" @default.
• W2316688317 modified "2023-10-10" @default.
• W2316688317 title "Hydrogen-Bond Symmetry in Difluoromaleate Monoanion" @default.
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• W2316688317 doi "https://doi.org/10.1021/ja2117848" @default.
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