FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2316691336> ?p ?o ?g. }

• W2316691336 endingPage "8583" @default.
• W2316691336 startingPage "8572" @default.
• W2316691336 abstract "The effect of particle size on the primary charging behavior of a suite of monodisperse nanometer diameter (4, 20, and 40 nm) anatase samples has been quantitatively examined with macroscopic experimental studies. The experimental results were evaluated using surface complexation modeling, which explicitly incorporated corresponding molecular-scale information from density functional theory (DFT) simulation studies. Potentiometric titrations were completed in NaCl media, at five ionic strengths (from 0.005 to 0.3 m), and over a wide pH range (3–11), at a temperature of 25 °C. From the experimental results, the pH of zero net proton charge (pHznpc) for the 4 and 20 nm diameter samples was 6.42, whereas the pHznpc was 6.22 for the 40 nm sample. The slopes of the net proton charge curves increased with an increase in particle size. Multisite surface complexation and charge distribution (CD) models, with a Basic Stern layer description of the electric double layer, were developed to describe all experimental data. Fits to the experimental data included an inner-sphere Na-bidentate species, an outer-sphere Na-monodentate species, and outer-sphere Cl-monodentate species. DFT simulations found the Na-bidentate species to be the most stable species on the (101) anatase surface (the predominant crystal face). The CD value for the Na-bidentate species was calculated using a bond valence interpretation of the DFT-optimized geometry. The Stern layer capacitance value varied systematically with particle size. The collective experimental and modeling studies show that subtle differences exist in the interface reactivity of nanometer diameter anatase samples. These results should help to further elucidate an understanding of the solid–aqueous solution interface reactivity of nanosized particles." @default.
• W2316691336 created "2016-06-24" @default.
• W2316691336 creator A5036477452 @default.
• W2316691336 creator A5038523045 @default.
• W2316691336 creator A5081157086 @default.
• W2316691336 date "2013-06-24" @default.
• W2316691336 modified "2023-09-26" @default.
• W2316691336 title "Anatase Nanoparticle Surface Reactivity in NaCl Media: A CD–MUSIC Model Interpretation of Combined Experimental and Density Functional Theory Studies" @default.
• W2316691336 cites W1963779270 @default.
• W2316691336 cites W1968426044 @default.
• W2316691336 cites W1968993609 @default.
• W2316691336 cites W1972327435 @default.
• W2316691336 cites W1974082844 @default.
• W2316691336 cites W1974670654 @default.
• W2316691336 cites W1976140311 @default.
• W2316691336 cites W1976380918 @default.
• W2316691336 cites W1978120782 @default.
• W2316691336 cites W1978215404 @default.
• W2316691336 cites W1979389443 @default.
• W2316691336 cites W1986173741 @default.
• W2316691336 cites W1986492345 @default.
• W2316691336 cites W1989992912 @default.
• W2316691336 cites W1992691566 @default.
• W2316691336 cites W2001103737 @default.
• W2316691336 cites W2001242965 @default.
• W2316691336 cites W2004466896 @default.
• W2316691336 cites W2005241888 @default.
• W2316691336 cites W2005741148 @default.
• W2316691336 cites W2006626976 @default.
• W2316691336 cites W2006907984 @default.
• W2316691336 cites W2008498887 @default.
• W2316691336 cites W2010083373 @default.
• W2316691336 cites W2014119798 @default.
• W2316691336 cites W2018148696 @default.
• W2316691336 cites W2019009962 @default.
• W2316691336 cites W2021625632 @default.
• W2316691336 cites W2031036131 @default.
• W2316691336 cites W2034816114 @default.
• W2316691336 cites W2036122636 @default.
• W2316691336 cites W2046740336 @default.
• W2316691336 cites W2047197195 @default.
• W2316691336 cites W2053193410 @default.
• W2316691336 cites W2056294493 @default.
• W2316691336 cites W2057697660 @default.
• W2316691336 cites W2061535118 @default.
• W2316691336 cites W2061987970 @default.
• W2316691336 cites W2078874506 @default.
• W2316691336 cites W2079468659 @default.
• W2316691336 cites W2083222334 @default.
• W2316691336 cites W2084587981 @default.
• W2316691336 cites W2086723506 @default.
• W2316691336 cites W2087301986 @default.
• W2316691336 cites W2089469157 @default.
• W2316691336 cites W2090081099 @default.
• W2316691336 cites W2091633783 @default.
• W2316691336 cites W2093767093 @default.
• W2316691336 cites W2099606293 @default.
• W2316691336 cites W2129754053 @default.
• W2316691336 cites W2144971922 @default.
• W2316691336 cites W2169670761 @default.
• W2316691336 cites W2334893687 @default.
• W2316691336 cites W4230748614 @default.
• W2316691336 cites W4297741038 @default.
• W2316691336 doi "https://doi.org/10.1021/la4011955" @default.
• W2316691336 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23745739" @default.
• W2316691336 hasPublicationYear "2013" @default.
• W2316691336 type Work @default.
• W2316691336 sameAs 2316691336 @default.
• W2316691336 citedByCount "10" @default.
• W2316691336 countsByYear W23166913362015 @default.
• W2316691336 countsByYear W23166913362016 @default.
• W2316691336 countsByYear W23166913362019 @default.
• W2316691336 countsByYear W23166913362020 @default.
• W2316691336 countsByYear W23166913362022 @default.
• W2316691336 countsByYear W23166913362023 @default.
• W2316691336 crossrefType "journal-article" @default.
• W2316691336 hasAuthorship W2316691336A5036477452 @default.
• W2316691336 hasAuthorship W2316691336A5038523045 @default.
• W2316691336 hasAuthorship W2316691336A5081157086 @default.
• W2316691336 hasConcept C113196181 @default.
• W2316691336 hasConcept C115624301 @default.
• W2316691336 hasConcept C121332964 @default.
• W2316691336 hasConcept C147597530 @default.
• W2316691336 hasConcept C147789679 @default.
• W2316691336 hasConcept C150708132 @default.
• W2316691336 hasConcept C152365726 @default.
• W2316691336 hasConcept C161790260 @default.
• W2316691336 hasConcept C178516000 @default.
• W2316691336 hasConcept C178790620 @default.
• W2316691336 hasConcept C185592680 @default.
• W2316691336 hasConcept C2777402863 @default.
• W2316691336 hasConcept C2780358262 @default.
• W2316691336 hasConcept C62520636 @default.
• W2316691336 hasConcept C65165184 @default.
• W2316691336 hasConcept C8010536 @default.
• W2316691336 hasConceptScore W2316691336C113196181 @default.
• W2316691336 hasConceptScore W2316691336C115624301 @default.
• W2316691336 hasConceptScore W2316691336C121332964 @default.

• next