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• W2316738713 abstract "A general synthetic route toward a diazatricyclic core common to the madangamine family is described. Ring-closing metathesis and palladium-catalyzed cycloisomerization provided the cis-fused diazadecalin structure, accompanied by formation of the N-Boc-enamine, which was utilized as an N-acyliminium ion equivalent. Direct cyclization from the N-Boc-enamine was achieved through the in situ formation of an N,O-acetal." @default.
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• W2316738713 date "2015-03-27" @default.
• W2316738713 modified "2023-09-26" @default.
• W2316738713 title "Synthesis of Diazatricyclic Common Structure of Madangamine Alkaloids" @default.
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• W2316738713 doi "https://doi.org/10.1021/acs.orglett.5b00661" @default.
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